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Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds
Jiang, Quanbin1; Guo, Tenglong1; Yu, Zhengkun1,2
关键词Asymmetric Catalysis Copper Enones Homogeneous Catalysis Ketones
刊名CHEMCATCHEM
2015-02-01
DOI10.1002/cctc.201402823
7期:4页:660-665
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; BORON CONJUGATE ADDITIONS ; ENANTIOSELECTIVE SYNTHESIS ; SATURATED KETONES ; BOND FORMATION ; BORATION ; ESTERS ; ALCOHOLS ; OXIDATION ; ENONES
英文摘要The Cu-catalyzed, one-pot tandem (asymmetric) borylation of -chloroalkyl aryl ketones via the insitu generated acyclic enones with bis(pinacolato)diboron was achieved efficiently to reach up to 97% yield and 99% enantioselectivity for the formal sp(3) CCl borylation products. The present methodology provides an efficient alternative route to (chiral) alkylboron compounds.
语种英语
WOS记录号WOS:000349917900017
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145962
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
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GB/T 7714
Jiang, Quanbin,Guo, Tenglong,Yu, Zhengkun. Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds[J]. CHEMCATCHEM,2015,7(4):660-665.
APA Jiang, Quanbin,Guo, Tenglong,&Yu, Zhengkun.(2015).Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds.CHEMCATCHEM,7(4),660-665.
MLA Jiang, Quanbin,et al."Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds".CHEMCATCHEM 7.4(2015):660-665.
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