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题名: Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles
作者: Zhan, Ensheng1;  Chen, Chunhui1;  Li, Yong1;  Shen, Wenjie1
刊名: CATALYSIS SCIENCE & TECHNOLOGY
发表日期: 2015
DOI: 10.1039/c4cy00900b
卷: 5, 期:2, 页:650-659
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Heterogeneous asymmetric hydrogenation of C=O and C=C bonds over chiral molecule-modified metal particles represents an important route for the production of chiral compounds. In this mini review, we first briefly introduced the background of heterogeneous asymmetric hydrogenation and the remaining challenges in this field. Then, we highlighted recent important progress in the understanding of the reaction mechanism in terms of the acid-base properties of supports and the effects of the size/shape of metal particles. Finally, we summarized the possible models proposed for the substrate-modifier adsorption and their interaction in asymmetric hydrogenation reactions.
关键词[WOS]: CINCHONIDINE-MODIFIED PALLADIUM ;  ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS ;  ENANTIO-SELECTIVE HYDROGENATION ;  MODIFIED PD CATALYSTS ;  MODIFIED PD/AL2O3 CATALYSTS ;  MODIFIED PD/TIO2 CATALYSTS ;  BED REACTOR SYSTEM ;  ENANTIOSELECTIVE HYDROGENATION ;  (E)-ALPHA-PHENYLCINNAMIC ACID ;  ACTIVATED KETONES
语种: 英语
WOS记录号: WOS:000348937900003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145997
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Zhan, Ensheng,Chen, Chunhui,Li, Yong,et al. Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles[J]. CATALYSIS SCIENCE & TECHNOLOGY,2015,5(2):650-659.
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