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Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes
Wei, Haisheng1,2; Wei, Xing1; Yang, Xiaofeng1; Yin, Guangzhao3; Wang, Aiqin1; Liu, Xiaoyan1; Huang, Yanqiang1; Zhang, Tao1
关键词Gold-nickel Alloy Chemoselective Hydrogenation Nitroarenes
刊名CHINESE JOURNAL OF CATALYSIS
2015-02-01
DOI10.1016/S1872-2067(14)60254-0
36期:2页:160-167
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]CO OXIDATION ; NITRO-COMPOUNDS ; MESOPOROUS SUPPORT ; GOLD ; NANOPARTICLES ; EFFICIENT ; CHLORONITROBENZENE ; DECOMPOSITION ; DESIGN
英文摘要A modified two-step approach was developed for the synthesis of uniform and highly dispersed Au-Ni alloy nanoparticles on a silica support. The supported Au-Ni alloy nanoparticles were investigated for the chemoselective hydrogenation of substituted nitroarenes, which showed a strong synergistic effect between Au and Ni. The best catalyst was AuNi3/SiO2 that afforded a selectivity to 3-vinylaniline of 93.0% at a 3-nitrostyrene conversion of 90.8% after 70 mm under mild conditions. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000349202600005
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145999
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Liaoning, Peoples R China
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Wei, Haisheng,Wei, Xing,Yang, Xiaofeng,et al. Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(2):160-167.
APA Wei, Haisheng.,Wei, Xing.,Yang, Xiaofeng.,Yin, Guangzhao.,Wang, Aiqin.,...&Zhang, Tao.(2015).Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes.CHINESE JOURNAL OF CATALYSIS,36(2),160-167.
MLA Wei, Haisheng,et al."Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes".CHINESE JOURNAL OF CATALYSIS 36.2(2015):160-167.
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