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Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds
Sohail, Muhammad; Zhang, Yixin; Liu, Wujun; Chen, Qin; Zhao, Zongbao K.
刊名RSC ADVANCES
2015
DOI10.1039/c4ra12417k
5期:22页:17014-17017
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]CONJUGATE ADDITION ; NATURAL PHOSPHATES ; BRONSTED ACIDS ; TETRAHYDROFURAN ; ALCOHOLS ; ANALOGS ; POLYMERIZATION ; TRANSFORMATION ; BIOSYNTHESIS ; COMPLEXES
英文摘要Novel alpha-bromo-beta-phosphoalkoxylated carbonyl compounds were produced in moderate to excellent yields via highly selective four-component reaction involving NBS, a cyclic ether, an organic phosphate and an aromatic alpha,beta-unsaturated carbonyl compound. A number of experimental observations suggested that the reaction is likely initiated by an acid mediated nucleophilic conjugate addition followed by electrophilic trapping the enol intermediate and subsequent ring-opening of the cyclic ether.
语种英语
WOS记录号WOS:000349556700052
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146003
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Div Biotechnol, Dalian 116032, Peoples R China
推荐引用方式
GB/T 7714
Sohail, Muhammad,Zhang, Yixin,Liu, Wujun,et al. Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds[J]. RSC ADVANCES,2015,5(22):17014-17017.
APA Sohail, Muhammad,Zhang, Yixin,Liu, Wujun,Chen, Qin,&Zhao, Zongbao K..(2015).Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds.RSC ADVANCES,5(22),17014-17017.
MLA Sohail, Muhammad,et al."Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds".RSC ADVANCES 5.22(2015):17014-17017.
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