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题名: Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds
作者: Sohail, Muhammad1;  Zhang, Yixin1;  Liu, Wujun1;  Chen, Qin1;  Zhao, Zongbao K.1
刊名: RSC ADVANCES
发表日期: 2015
DOI: 10.1039/c4ra12417k
卷: 5, 期:22, 页:17014-17017
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Novel alpha-bromo-beta-phosphoalkoxylated carbonyl compounds were produced in moderate to excellent yields via highly selective four-component reaction involving NBS, a cyclic ether, an organic phosphate and an aromatic alpha,beta-unsaturated carbonyl compound. A number of experimental observations suggested that the reaction is likely initiated by an acid mediated nucleophilic conjugate addition followed by electrophilic trapping the enol intermediate and subsequent ring-opening of the cyclic ether.
关键词[WOS]: CONJUGATE ADDITION ;  NATURAL PHOSPHATES ;  BRONSTED ACIDS ;  TETRAHYDROFURAN ;  ALCOHOLS ;  ANALOGS ;  POLYMERIZATION ;  TRANSFORMATION ;  BIOSYNTHESIS ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000349556700052
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146003
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Biotechnol, Dalian 116032, Peoples R China

Recommended Citation:
Sohail, Muhammad,Zhang, Yixin,Liu, Wujun,et al. Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds[J]. RSC ADVANCES,2015,5(22):17014-17017.
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