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Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds
Sohail, Muhammad; Zhang, Yixin; Liu, Wujun; Chen, Qin; Zhao, Zongbao K.
Source PublicationRSC ADVANCES
2015
DOI10.1039/c4ra12417k
Volume5Issue:22Pages:17014-17017
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCONJUGATE ADDITION ; NATURAL PHOSPHATES ; BRONSTED ACIDS ; TETRAHYDROFURAN ; ALCOHOLS ; ANALOGS ; POLYMERIZATION ; TRANSFORMATION ; BIOSYNTHESIS ; COMPLEXES
AbstractNovel alpha-bromo-beta-phosphoalkoxylated carbonyl compounds were produced in moderate to excellent yields via highly selective four-component reaction involving NBS, a cyclic ether, an organic phosphate and an aromatic alpha,beta-unsaturated carbonyl compound. A number of experimental observations suggested that the reaction is likely initiated by an acid mediated nucleophilic conjugate addition followed by electrophilic trapping the enol intermediate and subsequent ring-opening of the cyclic ether.
Language英语
WOS IDWOS:000349556700052
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146003
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Div Biotechnol, Dalian 116032, Peoples R China
Recommended Citation
GB/T 7714
Sohail, Muhammad,Zhang, Yixin,Liu, Wujun,et al. Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds[J]. RSC ADVANCES,2015,5(22):17014-17017.
APA Sohail, Muhammad,Zhang, Yixin,Liu, Wujun,Chen, Qin,&Zhao, Zongbao K..(2015).Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds.RSC ADVANCES,5(22),17014-17017.
MLA Sohail, Muhammad,et al."Four-component alpha-bromo-beta-phosphoalkoxylation of aromatic alpha,beta-unsaturated carbonyl compounds".RSC ADVANCES 5.22(2015):17014-17017.
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