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题名: Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins
作者: Wu, Ping1;  Wang, Liandi1;  Wu, Kaikai1;  Yu, Zhengkun1, 2
刊名: ORGANIC LETTERS
发表日期: 2015-02-20
DOI: 10.1021/ol503731s
卷: 17, 期:4, 页:868-871
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Bronsted acid p-(TsOHH2O)-H-.-catalyzed hydrovinylation of styrenes with internal olefins alpha-oxo ketene dithioacetals was efficiently achieved in the presence of N-phenylselenophthalimide (N-PSP), regioselectively affording Markovnikov phenylselenative hydrovinylation products through PhSe transfer of the phenylseleno ketene dithioacetal intermediates. Radical reduction of the resultant PhSe-alkyl-substituted ketene dithioacetals with AIBN/n-Bu3SnH gave the corresponding anti-Markovnikov hydrovinylation products formally from the linear codimerization of styrenes and the internal olefins.
关键词[WOS]: OXO KETENE DITHIOACETALS ;  ASYMMETRIC HYDROVINYLATION ;  EFFICIENT SYNTHESIS ;  ADDITION-REACTIONS ;  RUTHENIUM-COMPLEX ;  BOND ACTIVATION ;  IRIDIUM COMPLEX ;  ALKENES ;  DIMERIZATION ;  CARBON
语种: 英语
WOS记录号: WOS:000349942600027
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146041
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Wu, Ping,Wang, Liandi,Wu, Kaikai,et al. Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins[J]. ORGANIC LETTERS,2015,17(4):868-871.
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