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题名: Iridium- and Rhodium-Catalyzed C-H Activation and Formyl Alkynylation of Benzaldehydes under Chelation-Assistance
作者: Wang, He1;  Xie, Fang1;  Qi, Zisong1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2015-02-20
DOI: 10.1021/acs.orglett.5b00027
卷: 17, 期:4, 页:920-923
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Mild and efficient synthesis of ynones via Ir(III)- and Rh(III)-catalyzed, chelation-assisted formyl C-H alkynylation of benzaldehydes has been achieved using hypervalent iodine-alkyne reagents. Rhodium and iridium catalysis exhibited complementary substrate scope.
关键词[WOS]: 3-COMPONENT PYRIMIDINE SYNTHESIS ;  BOND ACTIVATION ;  INTERMOLECULAR HYDROACYLATION ;  SONOGASHIRA REACTION ;  TERMINAL ALKYNES ;  ACID-CHLORIDES ;  COUPLING REACTIONS ;  INTERNAL ALKYNES ;  ROOM-TEMPERATURE ;  ACYL CHLORIDES
语种: 英语
WOS记录号: WOS:000349942600040
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146044
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, He,Xie, Fang,Qi, Zisong,et al. Iridium- and Rhodium-Catalyzed C-H Activation and Formyl Alkynylation of Benzaldehydes under Chelation-Assistance[J]. ORGANIC LETTERS,2015,17(4):920-923.
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