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题名: Fabrication of ZnO with tunable morphology through a facile treatment of Zn-based coordination polymers
作者: Su, Panpan;  Zhao, Jiao;  Rong, Feng;  Li, Can1;  Yang, Qihua
关键词: ZnO ;  coordination polymers ;  hydrothermal method ;  micro and nanostructure ;  specific morphology
刊名: SCIENCE CHINA-CHEMISTRY
发表日期: 2015-03-01
DOI: 10.1007/s11426-014-5290-9
卷: 58, 期:3, 页:411-416
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The morphology and structure of zinc oxide (ZnO), one of the important semiconductors, are relevant to its properties and applications. The preparation of ZnO with tunable morphology and desired structure is an attractive topic in the field of material synthesis. This work reports a facile method for the synthesis of ZnO with controllable morphology and crystal orientation using Zn-based coordination polymer particles (Zn-CPP) as precursors. Using hydrothermal method, Zn-CPP with morphologies of microrod, nanoplate, flower-like, arrow-tipped microsheet, and square cylinder were successfully synthesized via the coordination between metal ions Zn2+ and organic ligand 1,4,5,8-naphthalenetetracarboxylic dianhydride in aqueous solution. Subsequent thermal treatment of the Zn-CPP successfully resulted in the formation of porous ZnO with similar morphology to Zn-CPP. It is also found that the ZnO with enhanced (002) orientation could be obtained from Zn-CPP with preferred (002) orientation. This strategy could be extended for the preparation of other metal oxides with desired shape and structure.
关键词[WOS]: OXIDE NANOPARTICLES ;  NANOWIRE ARRAYS ;  NANOCRYSTALS ;  DYE ;  PHOTOLUMINESCENCE ;  DEPOSITION ;  NANORODS ;  GROWTH ;  ROUTE
语种: 英语
WOS记录号: WOS:000350336500006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146055
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Su, Panpan,Zhao, Jiao,Rong, Feng,et al. Fabrication of ZnO with tunable morphology through a facile treatment of Zn-based coordination polymers[J]. SCIENCE CHINA-CHEMISTRY,2015,58(3):411-416.
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