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Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane
Che, Penghua1,2; Lu, Fang1; Si, Xiaoqin1,2; Xu, Jie1
Source PublicationRSC ADVANCES
2015
DOI10.1039/c4ra15919e
Volume5Issue:31Pages:24139-24143
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordAEROBIC OXIDATION ; MILD CONDITIONS ; DIMETHYL ETHER ; ISOSORBIDE ; CONVERSION ; GLYCEROL ; SOLVENTS ; ZEOLITE
Abstract1,2-Dimethoxyethane is explored for the first time as etherification agent for the acid-catalyzed synthesis of methyl ethers from biomass-derived hydroxyl compounds. H3PW12O40 catalyst can provide the formation of isosorbide methyl ethers with 80% GC yield from isosorbide. The acid catalyst type and acid amount are of critical importance in improving etherification reactivities of hydroxyl groups with 1,2-dimethoxyethane.
Language英语
WOS IDWOS:000351236300020
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146083
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Che, Penghua,Lu, Fang,Si, Xiaoqin,et al. Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane[J]. RSC ADVANCES,2015,5(31):24139-24143.
APA Che, Penghua,Lu, Fang,Si, Xiaoqin,&Xu, Jie.(2015).Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane.RSC ADVANCES,5(31),24139-24143.
MLA Che, Penghua,et al."Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane".RSC ADVANCES 5.31(2015):24139-24143.
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