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题名: Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane
作者: Che, Penghua1, 2;  Lu, Fang1;  Si, Xiaoqin1, 2;  Xu, Jie1
刊名: RSC ADVANCES
发表日期: 2015
DOI: 10.1039/c4ra15919e
卷: 5, 期:31, 页:24139-24143
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: 1,2-Dimethoxyethane is explored for the first time as etherification agent for the acid-catalyzed synthesis of methyl ethers from biomass-derived hydroxyl compounds. H3PW12O40 catalyst can provide the formation of isosorbide methyl ethers with 80% GC yield from isosorbide. The acid catalyst type and acid amount are of critical importance in improving etherification reactivities of hydroxyl groups with 1,2-dimethoxyethane.
关键词[WOS]: AEROBIC OXIDATION ;  MILD CONDITIONS ;  DIMETHYL ETHER ;  ISOSORBIDE ;  CONVERSION ;  GLYCEROL ;  SOLVENTS ;  ZEOLITE
语种: 英语
WOS记录号: WOS:000351236300020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146083
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Che, Penghua,Lu, Fang,Si, Xiaoqin,et al. Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethane[J]. RSC ADVANCES,2015,5(31):24139-24143.
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