DICP OpenIR
Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen
He, Lei1,2; Liang, Binglian1,2; Li, Lin1; Yang, Xiaofeng1; Huang, Yanqiang1; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1
关键词Hydrogen Generation Hydrous Hydrazine Non-noble Metal Ni-ceo2 Ni-o-ce
刊名ACS CATALYSIS
2015-03-01
DOI10.1021/acscatal.5b00143
5期:3页:1623-1628
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]HIGHLY EFFICIENT CATALYST ; ROOM-TEMPERATURE ; H-2 PRODUCTION ; AMBIENT CONDITIONS ; CO OXIDATION ; GENERATION ; NI ; STORAGE ; NANOPARTICLES ; SUPPORT
英文摘要Hydrous hydrazine is identified as a hydrogen reservoir owing to its high content of hydrogen (8.0 wt %). Its selective decomposition under mild conditions is the key for quick H-2 release. Modifying Ni nanoparticles with a small amount of CeO2 (8.0 mol %) resulted in a 3-fold increase of turnover frequency (TOF) and an enhancement of H-2 selectivity from 67% to above 99%. This improvement was due to the modification of Ni with CeO2 nearby through strong metal-support interaction (e.g., Ni-O-Ce structure). Furthermore, this promoting effect was extended to other oxides which can form strong metal-support interaction with Ni, such as ZrO2, MgO, and La2O3.
语种英语
WOS记录号WOS:000350843500028
引用统计
被引频次:49[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146084
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
He, Lei,Liang, Binglian,Li, Lin,et al. Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen[J]. ACS CATALYSIS,2015,5(3):1623-1628.
APA He, Lei.,Liang, Binglian.,Li, Lin.,Yang, Xiaofeng.,Huang, Yanqiang.,...&Zhang, Tao.(2015).Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen.ACS CATALYSIS,5(3),1623-1628.
MLA He, Lei,et al."Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen".ACS CATALYSIS 5.3(2015):1623-1628.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[He, Lei]的文章
[Liang, Binglian]的文章
[Li, Lin]的文章
百度学术
百度学术中相似的文章
[He, Lei]的文章
[Liang, Binglian]的文章
[Li, Lin]的文章
必应学术
必应学术中相似的文章
[He, Lei]的文章
[Liang, Binglian]的文章
[Li, Lin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。