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Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes
Li, Shanshan1,2; Li, Ning1; Li, Guangyi1; Li, Lin1; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Xu, Guoliang1; Zhang, Tao1
关键词Lignocellulose Renewable Diesel Titanate Nanotube Hydroxyallcylation/alkylation Hydrodeoxygenation
刊名APPLIED CATALYSIS B-ENVIRONMENTAL
2015-07-01
DOI10.1016/j.apcatb.2015.01.022
170页:124-134
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]HIGH-QUALITY DIESEL ; BIOMASS PLATFORM MOLECULES ; TRANSPORTATION FUELS ; ETHYLENE-GLYCOL ; MILD CONDITIONS ; LIQUID ALKANES ; NO REDUCTION ; SOLID ACID ; EXCESS O-2 ; CONVERSION
英文摘要Protonated titanate nanotube (PINT) was first reported as a good catalyst for the hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) and n-butanal from lignocellulose. Compared with other inorganic solid acids, PTNT has higher catalytic activity and efficiency. Over it, high yield of HAA product (77%) was achieved under mild reaction conditions. PTNT is also effective for the HAA (or alkylation) reactions between 2-MF and other lignocellulosic carbonyl compounds. According to the characterization results, the hydrothermal treatment of TiO2 P25 with NaOH solution and subsequent acidification significantly increases its BET surface area and the amount of acid sites on the surface of catalyst. Moreover, these pretreatments also lead to the generation of strong acid sites and Bronsted acid sites on the surface of catalyst. All of these changes are responsible for the excellent performance of PTNT. As the final aim of this work, the HAA product of 2-MF and n-butanal was converted to diesel and jet fuel range brached alkanes by the hydrodeoxygenation (HDO) over zeolite loaded Ni catalysts. Among them, Ni/H-ZSM-5 demonstrated the best catalytic performance and good stability, which makes it a promising catalyst in future application. (C) 2015 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000351646200012
引用统计
被引频次:18[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146088
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Li, Shanshan,Li, Ning,Li, Guangyi,et al. Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2015,170:124-134.
APA Li, Shanshan.,Li, Ning.,Li, Guangyi.,Li, Lin.,Wang, Aiqin.,...&Zhang, Tao.(2015).Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes.APPLIED CATALYSIS B-ENVIRONMENTAL,170,124-134.
MLA Li, Shanshan,et al."Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes".APPLIED CATALYSIS B-ENVIRONMENTAL 170(2015):124-134.
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