DICP OpenIR
Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes
Li, Shanshan1,2; Li, Ning1; Li, Guangyi1; Li, Lin1; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Xu, Guoliang1; Zhang, Tao1
KeywordLignocellulose Renewable Diesel Titanate Nanotube Hydroxyallcylation/alkylation Hydrodeoxygenation
Source PublicationAPPLIED CATALYSIS B-ENVIRONMENTAL
2015-07-01
DOI10.1016/j.apcatb.2015.01.022
Volume170Pages:124-134
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordHIGH-QUALITY DIESEL ; BIOMASS PLATFORM MOLECULES ; TRANSPORTATION FUELS ; ETHYLENE-GLYCOL ; MILD CONDITIONS ; LIQUID ALKANES ; NO REDUCTION ; SOLID ACID ; EXCESS O-2 ; CONVERSION
AbstractProtonated titanate nanotube (PINT) was first reported as a good catalyst for the hydroxyalkylation/alkylation (HAA) of 2-methylfuran (2-MF) and n-butanal from lignocellulose. Compared with other inorganic solid acids, PTNT has higher catalytic activity and efficiency. Over it, high yield of HAA product (77%) was achieved under mild reaction conditions. PTNT is also effective for the HAA (or alkylation) reactions between 2-MF and other lignocellulosic carbonyl compounds. According to the characterization results, the hydrothermal treatment of TiO2 P25 with NaOH solution and subsequent acidification significantly increases its BET surface area and the amount of acid sites on the surface of catalyst. Moreover, these pretreatments also lead to the generation of strong acid sites and Bronsted acid sites on the surface of catalyst. All of these changes are responsible for the excellent performance of PTNT. As the final aim of this work, the HAA product of 2-MF and n-butanal was converted to diesel and jet fuel range brached alkanes by the hydrodeoxygenation (HDO) over zeolite loaded Ni catalysts. Among them, Ni/H-ZSM-5 demonstrated the best catalytic performance and good stability, which makes it a promising catalyst in future application. (C) 2015 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000351646200012
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146088
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Shanshan,Li, Ning,Li, Guangyi,et al. Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2015,170:124-134.
APA Li, Shanshan.,Li, Ning.,Li, Guangyi.,Li, Lin.,Wang, Aiqin.,...&Zhang, Tao.(2015).Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes.APPLIED CATALYSIS B-ENVIRONMENTAL,170,124-134.
MLA Li, Shanshan,et al."Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanes".APPLIED CATALYSIS B-ENVIRONMENTAL 170(2015):124-134.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Shanshan]'s Articles
[Li, Ning]'s Articles
[Li, Guangyi]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Shanshan]'s Articles
[Li, Ning]'s Articles
[Li, Guangyi]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Shanshan]'s Articles
[Li, Ning]'s Articles
[Li, Guangyi]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.