DICP OpenIR
The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)
Pan, Lu1; Gao, Xiao-Han1; Lv, Xue-Chuan1; Cao, Hui1; Tan, Zhi-Cheng2; Jiao, Yu-Juan1; Geng, Ren-Yong1; Luo, Guan-Hua1
KeywordRare Earth Complexes Cluster Structure Fluorescence
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
2015
DOI10.1080/00958972.2014.1000884
Volume68Issue:5Pages:823-834
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
WOS KeywordCRYSTAL-STRUCTURES ; MOLECULAR-STRUCTURE ; MAGNETIC-PROPERTIES ; METAL-COMPLEXES ; IMIDAZOLE ; LIGANDS ; COPPER(II) ; POLYMERS ; SERIES ; ANION
AbstractTwo heptanuclear trigonal prismatic polyhedra, [EuCu6(-OH)(3)(Gly)(6)Im(6)](ClO4)(6)3H(2)O and [SmCu6(-OH)(3)(Gly)(6)Im(6)](ClO4)(6)3H(2)O were synthesized through self-assembly of Eu3+(Sm3+), Cu2+, glycine, and imidazole in aqueous solution and characterized by X-ray single crystal diffraction. Both complexes crystallize in the rhombohedral R3 space group (a=b=15.8673 angstrom, c=23.4038 angstrom, V=5103.0(6)angstrom(3), Z=3) and (a=b=15.8749 angstrom, c=23.455 angstrom, V=5119.1(8)angstrom(3), Z=3). In the clusters, Sm3+ and Eu3+ ions are situated in the center of a prism formed by six copper ions and coordinate to nine oxygens with a tricapped trigonal prismatic coordination polyhedron. Six glycinato ligands and six imidazole terminal ligands (each coordinates to one Cu2+) construct the cluster. The fluorescent excitation and emission spectra showed that the complexes have strong ligand-based fluorescence.
Language英语
WOS IDWOS:000350968600007
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146097
Collection中国科学院大连化学物理研究所
Affiliation1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Coll Chem Engn & Environm, Fushun, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Pan, Lu,Gao, Xiao-Han,Lv, Xue-Chuan,et al. The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)[J]. JOURNAL OF COORDINATION CHEMISTRY,2015,68(5):823-834.
APA Pan, Lu.,Gao, Xiao-Han.,Lv, Xue-Chuan.,Cao, Hui.,Tan, Zhi-Cheng.,...&Luo, Guan-Hua.(2015).The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm).JOURNAL OF COORDINATION CHEMISTRY,68(5),823-834.
MLA Pan, Lu,et al."The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)".JOURNAL OF COORDINATION CHEMISTRY 68.5(2015):823-834.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Pan, Lu]'s Articles
[Gao, Xiao-Han]'s Articles
[Lv, Xue-Chuan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Pan, Lu]'s Articles
[Gao, Xiao-Han]'s Articles
[Lv, Xue-Chuan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Pan, Lu]'s Articles
[Gao, Xiao-Han]'s Articles
[Lv, Xue-Chuan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.