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Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose
Sheng, Xueru1,2; Li, Ning1; Li, Guangyi1; Wang, Wentao1; Yang, Jinfan1,2; Cong, Yu1; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1
刊名SCIENTIFIC REPORTS
2015-03-31
DOI10.1038/srep09565
5
收录类别SCI
文章类型Article
WOS标题词Science & Technology
类目[WOS]Multidisciplinary Sciences
研究领域[WOS]Science & Technology - Other Topics
关键词[WOS]HIGH-QUALITY DIESEL ; POT CATALYTIC CONVERSION ; RENEWABLE DIESEL ; TRANSPORTATION FUELS ; LIQUID ALKANES ; RANGE ALKANES ; BIO-OIL ; BIOMASS ; HEMICELLULOSE ; HYDRODEOXYGENATION
英文摘要For the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the Guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (HDO). The solvent-free Guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and Raney metals. Among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (MgAl-HT) and Raney Ni (or Raney Co) exhibited the best performances. Over them, high carbon yield (96.7%) of C-10 and C-15 oxygenates was achieved. The Guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of Ni catalysts. These alkanes have high densities (0.86 g mL(-1) and 0.91 g mL(-1)) and can be used as high density aviation fuels or additives to bio-jet fuel. Among the investigated HDO catalysts, the 35 wt.% Ni-SiO2-DP prepared by deposition-precipitation method exhibited the highest activity.
语种英语
WOS记录号WOS:000351947900001
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被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146121
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
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GB/T 7714
Sheng, Xueru,Li, Ning,Li, Guangyi,et al. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose[J]. SCIENTIFIC REPORTS,2015,5.
APA Sheng, Xueru.,Li, Ning.,Li, Guangyi.,Wang, Wentao.,Yang, Jinfan.,...&Zhang, Tao.(2015).Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose.SCIENTIFIC REPORTS,5.
MLA Sheng, Xueru,et al."Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose".SCIENTIFIC REPORTS 5(2015).
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