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题名: Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose
作者: Sheng, Xueru1, 2;  Li, Ning1;  Li, Guangyi1;  Wang, Wentao1;  Yang, Jinfan1, 2;  Cong, Yu1;  Wang, Aiqin1;  Wang, Xiaodong1;  Zhang, Tao1
刊名: SCIENTIFIC REPORTS
发表日期: 2015-03-31
DOI: 10.1038/srep09565
卷: 5
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
类目[WOS]: Multidisciplinary Sciences
研究领域[WOS]: Science & Technology - Other Topics
英文摘要: For the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the Guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (HDO). The solvent-free Guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and Raney metals. Among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (MgAl-HT) and Raney Ni (or Raney Co) exhibited the best performances. Over them, high carbon yield (96.7%) of C-10 and C-15 oxygenates was achieved. The Guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of Ni catalysts. These alkanes have high densities (0.86 g mL(-1) and 0.91 g mL(-1)) and can be used as high density aviation fuels or additives to bio-jet fuel. Among the investigated HDO catalysts, the 35 wt.% Ni-SiO2-DP prepared by deposition-precipitation method exhibited the highest activity.
关键词[WOS]: HIGH-QUALITY DIESEL ;  POT CATALYTIC CONVERSION ;  RENEWABLE DIESEL ;  TRANSPORTATION FUELS ;  LIQUID ALKANES ;  RANGE ALKANES ;  BIO-OIL ;  BIOMASS ;  HEMICELLULOSE ;  HYDRODEOXYGENATION
语种: 英语
WOS记录号: WOS:000351947900001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146121
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China

Recommended Citation:
Sheng, Xueru,Li, Ning,Li, Guangyi,et al. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose[J]. SCIENTIFIC REPORTS,2015,5.
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