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Preparation of Nitrogen-Doped Carbon Nanotubes with Different Morphologies from Melamine-Formaldehyde Resin
Yao, Yi1,2; Zhang, Bingqing3,4,5; Shi, Jingying1,3; Yang, Qihua1
关键词Carbon Nanotubes Nitrogen Doping Oxygen Reduction Reaction
刊名ACS APPLIED MATERIALS & INTERFACES
2015-04-08
DOI10.1021/acsaml.5b01233
7期:13页:7413-7420
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
关键词[WOS]OXYGEN REDUCTION REACTION ; CATALYST ; PERFORMANCE ; ELECTRODES ; CHEMISTRY ; MECHANISM ; ROUTE
英文摘要We report a facile method for the synthesis of nitrogen-doped carbon nanotubes (NCNTs) from melamine-formaldehyde (MR) resin using FeCl3 or supported FeCl3 as catalysts. The growth of NCNTs: follows a decomposition reconstruction mechanism, in which the polymer precursor would totally gasify during pyrolysis process and then transformed into carbon nanotubes. The morphology of he NCNTs could be adjusted via applying different catalyst supports and three kinds of carbon nanotubes with outer-diameter of 20-200 nm and morphologies of either bamboo-like or hollow interiors were obtained. Nitrogen atoms in the materials were mainly in the form of pyridinic and quaternary form while the formation of iron species sttongly depended on the interaction between iniri precursor and organic carbon/nitrogen sources. All MR resin,derived NCNTs are efficient toward oxygen reduction reaction (ORR). NCNTs prepared using FeCl3 as catalyst showed the highest ORR activity with half-wave potentials of -0.17 V, which is comparable with commercial Pt/C. This is probably because of a close contact between MR. resin and iron precursor could enhance the iron-ligand coordination strength and thus steadily improve the performance of the catalyst.
语种英语
WOS记录号WOS:000352751800043
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146165
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
4.S China Univ Technol, Key Lab Fuel Cell Technol Guangdong Prov, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
5.S China Univ Technol, Key Lab New Energy Technol Guangdong Univ, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
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Yao, Yi,Zhang, Bingqing,Shi, Jingying,et al. Preparation of Nitrogen-Doped Carbon Nanotubes with Different Morphologies from Melamine-Formaldehyde Resin[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(13):7413-7420.
APA Yao, Yi,Zhang, Bingqing,Shi, Jingying,&Yang, Qihua.(2015).Preparation of Nitrogen-Doped Carbon Nanotubes with Different Morphologies from Melamine-Formaldehyde Resin.ACS APPLIED MATERIALS & INTERFACES,7(13),7413-7420.
MLA Yao, Yi,et al."Preparation of Nitrogen-Doped Carbon Nanotubes with Different Morphologies from Melamine-Formaldehyde Resin".ACS APPLIED MATERIALS & INTERFACES 7.13(2015):7413-7420.
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