DICP OpenIR
Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water
Ren, Lanhui1,2,3; Wang, Lianyue1,2; Lv, Ying1,2; Shang, Sensen1,2,3; Chen, Bo1,2,3; Gao, Shuang1,2
Source PublicationGREEN CHEMISTRY
2015
DOI10.1039/c4gc02471k
Volume17Issue:4Pages:2369-2372
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordTERT-BUTYL HYDROPEROXIDE ; COMPLEX ; HYDROCARBONS ; EFFICIENT
AbstractDirect oxidation of 2,3-cyclopentenopyridine analogues to 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues was achieved using Mn(OTf)(2) as a catalyst and t-BuOOH (65% in H2O) as an oxidant at 25 degrees C in H2O with high yield and excellent chemoselectivity for the first time. The catalytic system was also used efficiently for the direct oxidation of substituted benzylpyridines and 2-ethylpyridine in t-BuOH.
Language英语
WOS IDWOS:000352724200041
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146194
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ren, Lanhui,Wang, Lianyue,Lv, Ying,et al. Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water[J]. GREEN CHEMISTRY,2015,17(4):2369-2372.
APA Ren, Lanhui,Wang, Lianyue,Lv, Ying,Shang, Sensen,Chen, Bo,&Gao, Shuang.(2015).Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water.GREEN CHEMISTRY,17(4),2369-2372.
MLA Ren, Lanhui,et al."Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water".GREEN CHEMISTRY 17.4(2015):2369-2372.
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