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题名: Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water
作者: Ren, Lanhui1, 2, 3;  Wang, Lianyue1, 2;  Lv, Ying1, 2;  Shang, Sensen1, 2, 3;  Chen, Bo1, 2, 3;  Gao, Shuang1, 2
刊名: GREEN CHEMISTRY
发表日期: 2015
DOI: 10.1039/c4gc02471k
卷: 17, 期:4, 页:2369-2372
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Direct oxidation of 2,3-cyclopentenopyridine analogues to 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues was achieved using Mn(OTf)(2) as a catalyst and t-BuOOH (65% in H2O) as an oxidant at 25 degrees C in H2O with high yield and excellent chemoselectivity for the first time. The catalytic system was also used efficiently for the direct oxidation of substituted benzylpyridines and 2-ethylpyridine in t-BuOH.
关键词[WOS]: TERT-BUTYL HYDROPEROXIDE ;  COMPLEX ;  HYDROCARBONS ;  EFFICIENT
语种: 英语
WOS记录号: WOS:000352724200041
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146194
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Ren, Lanhui,Wang, Lianyue,Lv, Ying,et al. Synthesis of 6,7-dihydro-5H-cyclopenta[b]pyridin-5-one analogues through manganese-catalyzed oxidation of the CH2 adjacent to pyridine moiety in water[J]. GREEN CHEMISTRY,2015,17(4):2369-2372.
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