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题名: Bronsted acid-catalyzed phenylselenenylation of internal olefins
作者: Wu, Ping1;  Huang, Fei1;  Lou, Jiang1;  Wang, Quannan1;  Liu, Zhuqing1;  Yu, Zhengkun1
关键词: Bronsted acid ;  Internal olefins ;  Phenylselenenylation ;  N-phenylselenophthalimide ;  Phenylseleno transfer
刊名: TETRAHEDRON LETTERS
发表日期: 2015-05-06
DOI: 10.1016/j.tetlet.2015.03.096
卷: 56, 期:19, 页:2488-2491
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Bronsted acid p-TsOH center dot H2O-catalyzed phenylselenenylation of alpha-oxo ketene dithioacetals was efficiently achieved, by using N-phenylselenophthalimide (N-PSP) as the phenylseleno reagent. The resultant selenated ketene dithioacetals reacted with styrene in the presence of the same acid to undergo PhSe group transfer, regioselectively affording Markovnikov-type PhSe-alkylated olefins. Their further transformation with phenylboronic acid, guanidine, and hydrazine offers a promising route to access S,Se-incorporated organic compounds. (C) 2015 Elsevier Ltd. All rights reserved.
关键词[WOS]: OXO KETENE DITHIOACETALS ;  STEREOSELECTIVE-SYNTHESIS ;  ORGANOSELENIUM CHEMISTRY ;  EFFICIENT SYNTHESIS ;  BOND ACTIVATION ;  ALKENES ;  CARBOCYCLIZATION ;  STYRENES ;  INDOLES ;  KETONES
语种: 英语
WOS记录号: WOS:000353751000025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146212
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Wu, Ping,Huang, Fei,Lou, Jiang,et al. Bronsted acid-catalyzed phenylselenenylation of internal olefins[J]. TETRAHEDRON LETTERS,2015,56(19):2488-2491.
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