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Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation
Wang, Xu; Lu, Sheng-mei; Li, Jun; Liu, Yan; Li, Can
刊名CATALYSIS SCIENCE & TECHNOLOGY
2015
DOI10.1039/c5cy00038f
5期:5页:2585-2589
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]POROUS ORGANIC POLYMERS ; MIYAURA COUPLING REACTION ; N-HETEROCYCLIC CARBENE ; HIGH-SURFACE-AREA ; HETEROGENEOUS CATALYST ; SYNTHETIC CONTROL ; FRAMEWORK ; NETWORKS ; NANOPARTICLES ; EPOXIDATION
英文摘要A series of chiral conjugated microporous polymers (CMPs) based on the chiral (R)-BINAP ligand (BINAP-CMPs) were synthesized with tunable BET surface areas. These solid catalysts show high activities and enantioselectivities for the asymmetric hydrogenation of beta-keto esters after coordination with ruthenium species. Moreover, CMPs can realize spatial isolation. Through preventing the formation of dimers and trimers, BINAP-CMPs show much higher activity than BINAP for the Ir-catalyzed asymmetric hydrogenation of quinaldine.
语种英语
WOS记录号WOS:000353641800006
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被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146222
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Wang, Xu,Lu, Sheng-mei,Li, Jun,et al. Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2015,5(5):2585-2589.
APA Wang, Xu,Lu, Sheng-mei,Li, Jun,Liu, Yan,&Li, Can.(2015).Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation.CATALYSIS SCIENCE & TECHNOLOGY,5(5),2585-2589.
MLA Wang, Xu,et al."Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation".CATALYSIS SCIENCE & TECHNOLOGY 5.5(2015):2585-2589.
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