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题名: Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation
作者: Wang, Xu1;  Lu, Sheng-mei1;  Li, Jun1;  Liu, Yan1;  Li, Can1
刊名: CATALYSIS SCIENCE & TECHNOLOGY
发表日期: 2015
DOI: 10.1039/c5cy00038f
卷: 5, 期:5, 页:2585-2589
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A series of chiral conjugated microporous polymers (CMPs) based on the chiral (R)-BINAP ligand (BINAP-CMPs) were synthesized with tunable BET surface areas. These solid catalysts show high activities and enantioselectivities for the asymmetric hydrogenation of beta-keto esters after coordination with ruthenium species. Moreover, CMPs can realize spatial isolation. Through preventing the formation of dimers and trimers, BINAP-CMPs show much higher activity than BINAP for the Ir-catalyzed asymmetric hydrogenation of quinaldine.
关键词[WOS]: POROUS ORGANIC POLYMERS ;  MIYAURA COUPLING REACTION ;  N-HETEROCYCLIC CARBENE ;  HIGH-SURFACE-AREA ;  HETEROGENEOUS CATALYST ;  SYNTHETIC CONTROL ;  FRAMEWORK ;  NETWORKS ;  NANOPARTICLES ;  EPOXIDATION
语种: 英语
WOS记录号: WOS:000353641800006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146222
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Xu,Lu, Sheng-mei,Li, Jun,et al. Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2015,5(5):2585-2589.
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