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Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes
Song, Guoyong; Li, Xingwei
刊名ACCOUNTS OF CHEMICAL RESEARCH
2015-04-01
DOI10.1021/acs.accounts.5b00077
48期:4页:1007-1020
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]C-H ACTIVATION ; N BOND FORMATION ; CHELATION-ASSISTANCE ; AZOMETHINE YLIDES ; ROOM-TEMPERATURE ; BENZOIC-ACIDS ; CARBON BONDS ; ALKYNES ; ALKENES ; ALKYNYLATION
英文摘要The possibility of developing new methods for the efficient construction of organic molecules via disconnections other than traditional functional group transformations has driven the interest in direct functionalization of C-H bonds. The ubiquity of C-H bonds makes such transformations attractive, but they also pose several challenges. The first is the reactivity and selectivity of C-H bonds. To achieve this, directing groups (DGs) are often installed that can enhance the effective concentration of the catalyst, leading to thermodynamically stable metallacyclic intermediates. However, the presence of a pendant directing group in the product is often undesirable and unnecessary. This may account for the limitation of applications of C-H functionalization reactions in more common and general uses. Thus, the development of removable or functionalizable directing groups is desirable. Another key problem is that the reactivity of the resulting M-C bond can be low, which may limit the scope of the coupling partners and hence limit the reaction patterns of C-H activation reactions.
语种英语
WOS记录号WOS:000353429400012
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146223
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Song, Guoyong,Li, Xingwei. Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes[J]. ACCOUNTS OF CHEMICAL RESEARCH,2015,48(4):1007-1020.
APA Song, Guoyong,&Li, Xingwei.(2015).Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes.ACCOUNTS OF CHEMICAL RESEARCH,48(4),1007-1020.
MLA Song, Guoyong,et al."Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes".ACCOUNTS OF CHEMICAL RESEARCH 48.4(2015):1007-1020.
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