DICP OpenIR
Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes
Song, Guoyong; Li, Xingwei
Source PublicationACCOUNTS OF CHEMICAL RESEARCH
2015-04-01
DOI10.1021/acs.accounts.5b00077
Volume48Issue:4Pages:1007-1020
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordC-H ACTIVATION ; N BOND FORMATION ; CHELATION-ASSISTANCE ; AZOMETHINE YLIDES ; ROOM-TEMPERATURE ; BENZOIC-ACIDS ; CARBON BONDS ; ALKYNES ; ALKENES ; ALKYNYLATION
AbstractThe possibility of developing new methods for the efficient construction of organic molecules via disconnections other than traditional functional group transformations has driven the interest in direct functionalization of C-H bonds. The ubiquity of C-H bonds makes such transformations attractive, but they also pose several challenges. The first is the reactivity and selectivity of C-H bonds. To achieve this, directing groups (DGs) are often installed that can enhance the effective concentration of the catalyst, leading to thermodynamically stable metallacyclic intermediates. However, the presence of a pendant directing group in the product is often undesirable and unnecessary. This may account for the limitation of applications of C-H functionalization reactions in more common and general uses. Thus, the development of removable or functionalizable directing groups is desirable. Another key problem is that the reactivity of the resulting M-C bond can be low, which may limit the scope of the coupling partners and hence limit the reaction patterns of C-H activation reactions.
Language英语
WOS IDWOS:000353429400012
Citation statistics
Cited Times:536[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146223
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Song, Guoyong,Li, Xingwei. Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes[J]. ACCOUNTS OF CHEMICAL RESEARCH,2015,48(4):1007-1020.
APA Song, Guoyong,&Li, Xingwei.(2015).Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes.ACCOUNTS OF CHEMICAL RESEARCH,48(4),1007-1020.
MLA Song, Guoyong,et al."Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes".ACCOUNTS OF CHEMICAL RESEARCH 48.4(2015):1007-1020.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Song, Guoyong]'s Articles
[Li, Xingwei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Song, Guoyong]'s Articles
[Li, Xingwei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Song, Guoyong]'s Articles
[Li, Xingwei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.