DICP OpenIR
Dynamic redox cycle of Cu-0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation
Ma, Xiangang1; Yang, Zhiqiang2; Liu, Xuebin2; Tan, Xingzhi2; Ge, Qingjie1
刊名RSC ADVANCES
2015
DOI10.1039/c5ra04389a
5期:47页:37581-37584
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SILICA-SUPPORTED COPPER ; VAPOR-PHASE HYDROGENATION ; DIMETHYL OXALATE ; ETHYLENE-GLYCOL ; CHEMOSELECTIVE HYDROGENATION ; STRUCTURAL EVOLUTION ; HMS CATALYST ; GEL METHOD ; CR OXIDE ; HYDROGENOLYSIS
英文摘要Esters (methyl acetate, ethyl acetate, dimethyl oxalate) can oxidize Cu-0 of the reduced Cu/SiO2 catalyst to Cu+ and the obtained Cu+ can be reduced back to Cu-0 by H-2 under reaction conditions. Cu-0 and Cu+ are in a dynamic cycle during ester hydrogenation. The ratio of Cu+/Cu-0 in the presence of esters under reaction conditions is probably different from that in the absence of esters under characterization conditions. The effect of the dynamic cycle on the Cu+/Cu-0 ratio should be taken into consideration when establishing the relationship between the Cu+/Cu-0 ratio and reaction performance.
语种英语
WOS记录号WOS:000353653200052
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146257
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.BP China Holdings Ltd, Energy Innovat Lab, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Ma, Xiangang,Yang, Zhiqiang,Liu, Xuebin,et al. Dynamic redox cycle of Cu-0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation[J]. RSC ADVANCES,2015,5(47):37581-37584.
APA Ma, Xiangang,Yang, Zhiqiang,Liu, Xuebin,Tan, Xingzhi,&Ge, Qingjie.(2015).Dynamic redox cycle of Cu-0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation.RSC ADVANCES,5(47),37581-37584.
MLA Ma, Xiangang,et al."Dynamic redox cycle of Cu-0 and Cu+ over Cu/SiO2 catalyst in ester hydrogenation".RSC ADVANCES 5.47(2015):37581-37584.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Ma, Xiangang]的文章
[Yang, Zhiqiang]的文章
[Liu, Xuebin]的文章
百度学术
百度学术中相似的文章
[Ma, Xiangang]的文章
[Yang, Zhiqiang]的文章
[Liu, Xuebin]的文章
必应学术
必应学术中相似的文章
[Ma, Xiangang]的文章
[Yang, Zhiqiang]的文章
[Liu, Xuebin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。