DICP OpenIR
Total synthesis of (+)-fusarisetin A
Huang, Jun1; Fang, Lichao1; Gong, Jianxian1; Li, Chuangchuang1; Yang, Zhen1,2,3
KeywordStereoselective Fusarisetin a Pauson-khand Reaction Trans-decalin Quaternary Stereocenter
Source PublicationTETRAHEDRON
2015-06-03
DOI10.1016/j.tet.2014.08.073
Volume71Issue:22Pages:3720-3733
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPAUSON-KHAND REACTION ; ENANTIOSELECTIVE TOTAL-SYNTHESIS ; DIELS-ALDER REACTION ; FUSARIUM TOXIN EQUISETIN ; FORMAL TOTAL-SYNTHESIS ; N-OXIDE ; CARBONYL-COMPOUNDS ; ABSOLUTE-CONFIGURATION ; ASYMMETRIC-SYNTHESIS ; CONJUGATE REDUCTION
AbstractHerein we report the full details of our efforts toward the application of Pauson-Khand reaction for the stereoselective construction of the trans-decalin subunit with a C16 quaternary stereocenter of fusarisetin A, which led to the asymmetric total synthesis of (+)-fusarisetin A. The developed chemistry provides an alternative strategy to the intramolecular Diels Alder reaction that has been employed for the synthesis of trans-decalin based natural products. (C) 2014 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000355051000023
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146264
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Minist Educ, Beijing 100871, Peoples R China
3.Peking Univ, Peking Tsinghua Ctr Life Sci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Huang, Jun,Fang, Lichao,Gong, Jianxian,et al. Total synthesis of (+)-fusarisetin A[J]. TETRAHEDRON,2015,71(22):3720-3733.
APA Huang, Jun,Fang, Lichao,Gong, Jianxian,Li, Chuangchuang,&Yang, Zhen.(2015).Total synthesis of (+)-fusarisetin A.TETRAHEDRON,71(22),3720-3733.
MLA Huang, Jun,et al."Total synthesis of (+)-fusarisetin A".TETRAHEDRON 71.22(2015):3720-3733.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Huang, Jun]'s Articles
[Fang, Lichao]'s Articles
[Gong, Jianxian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Huang, Jun]'s Articles
[Fang, Lichao]'s Articles
[Gong, Jianxian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Huang, Jun]'s Articles
[Fang, Lichao]'s Articles
[Gong, Jianxian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.