中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Total synthesis of (+)-fusarisetin A
作者: Huang, Jun1;  Fang, Lichao1;  Gong, Jianxian1;  Li, Chuangchuang1;  Yang, Zhen1, 2, 3
关键词: Stereoselective ;  Fusarisetin A ;  Pauson-Khand reaction ;  trans-Decalin ;  Quaternary stereocenter
刊名: TETRAHEDRON
发表日期: 2015-06-03
DOI: 10.1016/j.tet.2014.08.073
卷: 71, 期:22, 页:3720-3733
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Herein we report the full details of our efforts toward the application of Pauson-Khand reaction for the stereoselective construction of the trans-decalin subunit with a C16 quaternary stereocenter of fusarisetin A, which led to the asymmetric total synthesis of (+)-fusarisetin A. The developed chemistry provides an alternative strategy to the intramolecular Diels Alder reaction that has been employed for the synthesis of trans-decalin based natural products. (C) 2014 Elsevier Ltd. All rights reserved.
关键词[WOS]: PAUSON-KHAND REACTION ;  ENANTIOSELECTIVE TOTAL-SYNTHESIS ;  DIELS-ALDER REACTION ;  FUSARIUM TOXIN EQUISETIN ;  FORMAL TOTAL-SYNTHESIS ;  N-OXIDE ;  CARBONYL-COMPOUNDS ;  ABSOLUTE-CONFIGURATION ;  ASYMMETRIC-SYNTHESIS ;  CONJUGATE REDUCTION
语种: 英语
WOS记录号: WOS:000355051000023
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146264
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Minist Educ, Beijing 100871, Peoples R China
3.Peking Univ, Peking Tsinghua Ctr Life Sci, Beijing 100871, Peoples R China

Recommended Citation:
Huang, Jun,Fang, Lichao,Gong, Jianxian,et al. Total synthesis of (+)-fusarisetin A[J]. TETRAHEDRON,2015,71(22):3720-3733.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Huang, Jun]'s Articles
 [Fang, Lichao]'s Articles
 [Gong, Jianxian]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Huang, Jun]‘s Articles
 [Fang, Lichao]‘s Articles
 [Gong, Jianxian]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace