DICP OpenIR
Photophysical Properties of a Post-Self-Assembly Host/Guest Coordination Cage: Visible Light Driven Core-to-Cage Charge Transfer
Yang, Yang1; Chen, Jun-Sheng1,2; Liu, Jian-Yong1; Zhao, Guang-Jiu1; Liu, Lei1; Han, Ke-Li1; Cook, Timothy R.3; Stang, Peter J.4
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY LETTERS
2015-05-21
DOI10.1021/acs.jpclett.5b00783
Volume6Issue:10Pages:1942-1947
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS KeywordDENSITY-FUNCTIONAL CALCULATIONS ; BIMETALLIC PLATINUM COMPLEXES ; EXCITED-STATES ; WATER ; DESIGN ; PHOTOSENSITIZERS ; POLYMETALLAYNES ; METALLACYCLES ; FLUORESCENCE ; PERFORMANCE
AbstractSupramolecular systems are capable of unique photophysical properties due to possible interactions between subcomponents, such as between an encapsulated molecule and its cage in a host/guest environment. Here, we report that the encapsulation of a chromophore by a metallacage dramatically enhances its photophysical properties. In the visible region, the encapsulated photosensitizer achieves a 6.5-fold enhancement to its absorptivity. The triplet lifetime of the encapsulated photosensitizer is three times longer than that of its free analogue. These enhancements are attributed to two key factors: (i) encapsulation-induced core-to-cage charge transfer (CCCT) generates new visible-light absorbing states, accounting for the enhanced absorption, and (ii) the microenvironment inside the metallacage inhibits nonradiative decay processes, resulting in prolonged triplet lifetime. The CCCT arises from the electrostatic interaction between the delocalized electrons of the guest coronene and the positive charge associated with the metallacage host. The work herein provides insight into the CCCT phenomenon.
Language英语
WOS IDWOS:000355158600026
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146266
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
4.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Recommended Citation
GB/T 7714
Yang, Yang,Chen, Jun-Sheng,Liu, Jian-Yong,et al. Photophysical Properties of a Post-Self-Assembly Host/Guest Coordination Cage: Visible Light Driven Core-to-Cage Charge Transfer[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2015,6(10):1942-1947.
APA Yang, Yang.,Chen, Jun-Sheng.,Liu, Jian-Yong.,Zhao, Guang-Jiu.,Liu, Lei.,...&Stang, Peter J..(2015).Photophysical Properties of a Post-Self-Assembly Host/Guest Coordination Cage: Visible Light Driven Core-to-Cage Charge Transfer.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,6(10),1942-1947.
MLA Yang, Yang,et al."Photophysical Properties of a Post-Self-Assembly Host/Guest Coordination Cage: Visible Light Driven Core-to-Cage Charge Transfer".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 6.10(2015):1942-1947.
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