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Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity
Chen, Weidong1,2; Huang, Zhenguo; Wu, Guotao1; He, Teng1; Li, Zhao1; Chen, Juner1; Guo, Zaiping3; Liu, Huakun3; Chen, Ping1
刊名JOURNAL OF MATERIALS CHEMISTRY A
2015
DOI10.1039/c5ta01158b
3期:21页:11411-11416
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Energy & Fuels ; Materials Science
关键词[WOS]N-H COMPOUNDS ; THERMAL-DECOMPOSITION ; AMMONIA-BORANE ; HYPERGOLIC FUELS ; BOROHYDRIDE ; HYDROLYSIS ; TRIBORANE ; HYDRAZINE ; EFFICIENT ; HYDRIDES
英文摘要For chemical hydrogen storage, capacity is one key criterion that has spurred intense efforts to investigate compounds with high hydrogen content. The guanidinium cation and the octahydrotriborate anion possess 6 H+ and 8 H-, respectively. The combination of these two ions yields guanidinium octahydrotriborate with 13.8 wt% hydrogen. This paper presents its facile synthesis, as confirmed by B-11 and H-1 nuclear magnetic resonance spectroscopy. The results show that guanidinium octahydrotriborate is an ionic liquid with a melting point below -10 degrees C, which makes it a possible injectable/pumpable hydrogen carrier. It decomposes selectively to hydrogen, in stark contrast to the formation of various boranes from related solid octahydrotriborates. The much improved H-2 purity can be ascribed to the more effective combination of H+ and H-, and the higher H+/H- ratio in liquid guanidinium octahydrotriborate.
语种英语
WOS记录号WOS:000354952500030
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146267
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Univ Wollongong, Inst Superconducting & Elect Mat, North Wollongong, NSW 2522, Australia
推荐引用方式
GB/T 7714
Chen, Weidong,Huang, Zhenguo,Wu, Guotao,et al. Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(21):11411-11416.
APA Chen, Weidong.,Huang, Zhenguo.,Wu, Guotao.,He, Teng.,Li, Zhao.,...&Chen, Ping.(2015).Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity.JOURNAL OF MATERIALS CHEMISTRY A,3(21),11411-11416.
MLA Chen, Weidong,et al."Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity".JOURNAL OF MATERIALS CHEMISTRY A 3.21(2015):11411-11416.
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