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Aerobic oxidation of benzyl alcohols using a novel combination of N-hydroxyphthalimide (NHPI) with HNO3 and CuBr2
Chen, Bo1,2,3; Li, Jun1,2; Yang, Gang1,2; Gao, Shuang1,2
关键词Oxidation Alcohol Nhpi Copper Hno3 Oxygen
刊名RESEARCH ON CHEMICAL INTERMEDIATES
2015-06-01
DOI10.1007/s11164-013-1500-x
41期:6页:3929-3936
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]VANADIUM COCATALYSTS ; CARBONYL-COMPOUNDS ; MOLECULAR-OXYGEN ; MILD CONDITIONS ; NITRIC-ACID ; SELECTIVE OXIDATION ; SECONDARY ALCOHOLS ; ATOM ECONOMY ; EFFICIENT ; DIOXYGEN
英文摘要A new catalytic system for oxidation of alcohols with oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with HNO3 and CuBr2 has been developed. This system can effectively catalyze oxidation of primary benzylic alcohols to corresponding aldehydes with high selectivities (up to 100 %). A mechanism for the oxidation of alcohols catalyzed by NHPI/HNO3/CuBr2 is proposed.
语种英语
WOS记录号WOS:000355149900051
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146274
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Chen, Bo,Li, Jun,Yang, Gang,et al. Aerobic oxidation of benzyl alcohols using a novel combination of N-hydroxyphthalimide (NHPI) with HNO3 and CuBr2[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2015,41(6):3929-3936.
APA Chen, Bo,Li, Jun,Yang, Gang,&Gao, Shuang.(2015).Aerobic oxidation of benzyl alcohols using a novel combination of N-hydroxyphthalimide (NHPI) with HNO3 and CuBr2.RESEARCH ON CHEMICAL INTERMEDIATES,41(6),3929-3936.
MLA Chen, Bo,et al."Aerobic oxidation of benzyl alcohols using a novel combination of N-hydroxyphthalimide (NHPI) with HNO3 and CuBr2".RESEARCH ON CHEMICAL INTERMEDIATES 41.6(2015):3929-3936.
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