DICP OpenIR
Detection of Nitro-Based and Peroxide-Based Explosives by Fast Polarity-Switchable Ion Mobility Spectrometer with Ion Focusing in Vicinity of Faraday Detector
Zhou, Qinghua1,3; Peng, Liying1,3; Jiang, Dandan1,3; Wang, Xin1; Wang, Haiyan2; Li, Haiyang1
Source PublicationSCIENTIFIC REPORTS
2015-05-29
DOI10.1038/srep10659
Volume5
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordHEXAMETHYLENE TRIPEROXIDE DIAMINE ; SENSITIVE DETECTION ; RESOLVING POWER ; CHROMATOGRAPHY ; RESOLUTION ; DESIGN ; REGION ; HMTD ; GAS
AbstractIon mobility spectrometer (IMS) has been widely deployed for on-site detection of explosives. The common nitro-based explosives are usually detected by negative IMS while the emerging peroxide-based explosives are better detected by positive IMS. In this study, a fast polarityswitchable IMS was constructed to detect these two explosive species in a single measurement. As the large traditional Faraday detector would cause a trailing reactant ion peak (RIP), a Faraday detector with ion focusing in vicinity was developed by reducing the detector radius to 3.3 mm and increasing the voltage difference between aperture grid and its front guard ring to 591 V, which could remove trailing peaks from RIP without loss of signal intensity. This fast polarity-switchable IMS with ion focusing in vicinity of Faraday detector was employed to detect a mixture of 10 ng 2,4,6-trinitrotoluene (TNT) and 50 ng hexamethylene triperoxide diamine (HMTD) by polarity-switching, and the result suggested that [TNT-H]-and [HMTD+H](+) could be detected in a single measurement. Furthermore, the removal of trailing peaks from RIP by the Faraday detector with ion focusing in vicinity also promised the accurate identification of KClO4, KNO3 and S in common inorganic explosives, whose product ion peaks were fairly adjacent to RIP.
Language英语
WOS IDWOS:000355591200002
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146305
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Liaoning, Peoples R China
2.Jiangsu Prov Inst Qual & Safety Engn, Nanjing 210046, Jiangsu, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Qinghua,Peng, Liying,Jiang, Dandan,et al. Detection of Nitro-Based and Peroxide-Based Explosives by Fast Polarity-Switchable Ion Mobility Spectrometer with Ion Focusing in Vicinity of Faraday Detector[J]. SCIENTIFIC REPORTS,2015,5.
APA Zhou, Qinghua,Peng, Liying,Jiang, Dandan,Wang, Xin,Wang, Haiyan,&Li, Haiyang.(2015).Detection of Nitro-Based and Peroxide-Based Explosives by Fast Polarity-Switchable Ion Mobility Spectrometer with Ion Focusing in Vicinity of Faraday Detector.SCIENTIFIC REPORTS,5.
MLA Zhou, Qinghua,et al."Detection of Nitro-Based and Peroxide-Based Explosives by Fast Polarity-Switchable Ion Mobility Spectrometer with Ion Focusing in Vicinity of Faraday Detector".SCIENTIFIC REPORTS 5(2015).
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