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Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene
De Baerdemaeker, Trees1; Feyen, Mathias2; Mueller, Ulrich2; Yilmaz, Bilge3; Xiao, Feng-Shou4; Zhang, Weiping5; Yokoi, Toshiyuki6; Bao, Xinhe7; Gies, Hermann8; De Vos, Dirk E.1
KeywordEthanol 1 Zinc Silicate 3-butadiene Hemimorphite Heterogeneous Catalysis Silica Impregnation
Source PublicationACS CATALYSIS
2015-06-01
DOI10.1021/acscatal.5b00376
Volume5Issue:6Pages:3393-3397
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordMAGNESIUM-OXIDE ; METAL-OXIDES ; BUTADIENE ; HYDROXYAPATITE ; TRANSFORMATION ; SELECTIVITY ; BASICITY ; ACETONE ; LEBEDEV
AbstractSilica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.
Language英语
WOS IDWOS:000355964300025
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146308
Collection中国科学院大连化学物理研究所
Affiliation1.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium
2.BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany
3.BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA
4.Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China
5.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
6.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
7.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
8.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
Recommended Citation
GB/T 7714
De Baerdemaeker, Trees,Feyen, Mathias,Mueller, Ulrich,et al. Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene[J]. ACS CATALYSIS,2015,5(6):3393-3397.
APA De Baerdemaeker, Trees.,Feyen, Mathias.,Mueller, Ulrich.,Yilmaz, Bilge.,Xiao, Feng-Shou.,...&De Vos, Dirk E..(2015).Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene.ACS CATALYSIS,5(6),3393-3397.
MLA De Baerdemaeker, Trees,et al."Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene".ACS CATALYSIS 5.6(2015):3393-3397.
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