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题名: Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents
作者: Wang, He1;  Yu, Songjie1;  Qi, Zisong1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2015-06-05
DOI: 10.1021/acs.orglett.5b01232
卷: 17, 期:11, 页:2812-2815
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Rhodium(III)-catalyzed direct alkylation of arenes using commercially available alkyltrifluoroborates is disclosed. Oximes, heteroarenes, azomethines, N-nitrosoamines, and amides are viable directing groups to entail this transformation. The alkyl group in the boron reagent can be extended to primary alkyls, benzyl, and cycloalkyls, and the reaction proceeded with controllable mono- and dialkylation selectivity when both ortho C-H sites are accessible.
关键词[WOS]: PALLADIUM-CATALYZED ALKYLATION ;  SINGLE-ELECTRON TRANSMETALATION ;  CARBON-HYDROGEN BONDS ;  ARYL BORONIC ACIDS ;  ONE-POT SYNTHESIS ;  DIRECTING GROUP ;  N-PHENOXYACETAMIDES ;  REGIOSELECTIVE SYNTHESIS ;  ARYLBORON REAGENTS ;  ORGANIC-SYNTHESIS
语种: 英语
WOS记录号: WOS:000355962200063
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146322
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, He,Yu, Songjie,Qi, Zisong,et al. Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents[J]. ORGANIC LETTERS,2015,17(11):2812-2815.
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