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Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents
Wang, He; Yu, Songjie; Qi, Zisong; Li, Xingwei
Source PublicationORGANIC LETTERS
2015-06-05
DOI10.1021/acs.orglett.5b01232
Volume17Issue:11Pages:2812-2815
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPALLADIUM-CATALYZED ALKYLATION ; SINGLE-ELECTRON TRANSMETALATION ; CARBON-HYDROGEN BONDS ; ARYL BORONIC ACIDS ; ONE-POT SYNTHESIS ; DIRECTING GROUP ; N-PHENOXYACETAMIDES ; REGIOSELECTIVE SYNTHESIS ; ARYLBORON REAGENTS ; ORGANIC-SYNTHESIS
AbstractRhodium(III)-catalyzed direct alkylation of arenes using commercially available alkyltrifluoroborates is disclosed. Oximes, heteroarenes, azomethines, N-nitrosoamines, and amides are viable directing groups to entail this transformation. The alkyl group in the boron reagent can be extended to primary alkyls, benzyl, and cycloalkyls, and the reaction proceeded with controllable mono- and dialkylation selectivity when both ortho C-H sites are accessible.
Language英语
WOS IDWOS:000355962200063
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146322
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wang, He,Yu, Songjie,Qi, Zisong,et al. Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents[J]. ORGANIC LETTERS,2015,17(11):2812-2815.
APA Wang, He,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents.ORGANIC LETTERS,17(11),2812-2815.
MLA Wang, He,et al."Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents".ORGANIC LETTERS 17.11(2015):2812-2815.
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