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Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents
Wang, He; Yu, Songjie; Qi, Zisong; Li, Xingwei
刊名ORGANIC LETTERS
2015-06-05
DOI10.1021/acs.orglett.5b01232
17期:11页:2812-2815
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PALLADIUM-CATALYZED ALKYLATION ; SINGLE-ELECTRON TRANSMETALATION ; CARBON-HYDROGEN BONDS ; ARYL BORONIC ACIDS ; ONE-POT SYNTHESIS ; DIRECTING GROUP ; N-PHENOXYACETAMIDES ; REGIOSELECTIVE SYNTHESIS ; ARYLBORON REAGENTS ; ORGANIC-SYNTHESIS
英文摘要Rhodium(III)-catalyzed direct alkylation of arenes using commercially available alkyltrifluoroborates is disclosed. Oximes, heteroarenes, azomethines, N-nitrosoamines, and amides are viable directing groups to entail this transformation. The alkyl group in the boron reagent can be extended to primary alkyls, benzyl, and cycloalkyls, and the reaction proceeded with controllable mono- and dialkylation selectivity when both ortho C-H sites are accessible.
语种英语
WOS记录号WOS:000355962200063
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被引频次:44[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146322
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Wang, He,Yu, Songjie,Qi, Zisong,et al. Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents[J]. ORGANIC LETTERS,2015,17(11):2812-2815.
APA Wang, He,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents.ORGANIC LETTERS,17(11),2812-2815.
MLA Wang, He,et al."Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents".ORGANIC LETTERS 17.11(2015):2812-2815.
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