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Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations
Xie, Fang1; Zhang, Zhipeng1; Yu, Xinzhang1,2; Tang, Guodong1; Li, Xingwei1
关键词Arenes C-h Activation Copper Hypervalent Compounds Rhodium
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2015-06-15
DOI10.1002/anie.201502278
54期:25页:7405-7409
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ONE-POT SYNTHESIS ; ROOM-TEMPERATURE ; UNSYMMETRICAL LAMBDA(3)-IODANES ; CATALYZED FLUORINATION ; CHELATION-ASSISTANCE ; POLYVALENT IODINE ; ARYLBORONIC ACIDS ; COUPLING REACTION ; BOND ACTIVATION ; IODONIUM SALTS
英文摘要Diaryliodonium salts play an increasingly important role as an aryl source. Reported is the first synthesis of diaryliodoniums by rhodium(III)-catalyzed C-H hyperiodination of electron-poor arenes under chelation assistance. This C-I coupling reaction occurred at room temperature with high regio-selectivity and functional-group compatibility. Subsequent diversified nucleophilic functionalization of a diarylio-donium allowed facile construction of C-C, C-N, C-O, C-S, C-P and C-Br bonds, and in all cases the initial functionalization occurred at the arene containing the chelating-group.
语种英语
WOS记录号WOS:000356390300035
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146336
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Taiyuan Inst Technol, Dept Chem & Chem Engn, Taiyuan 030008, Peoples R China
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GB/T 7714
Xie, Fang,Zhang, Zhipeng,Yu, Xinzhang,et al. Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(25):7405-7409.
APA Xie, Fang,Zhang, Zhipeng,Yu, Xinzhang,Tang, Guodong,&Li, Xingwei.(2015).Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(25),7405-7409.
MLA Xie, Fang,et al."Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.25(2015):7405-7409.
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