中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations
作者: Xie, Fang1;  Zhang, Zhipeng1;  Yu, Xinzhang1, 2;  Tang, Guodong1;  Li, Xingwei1
关键词: arenes ;  C-H activation ;  copper ;  hypervalent compounds ;  rhodium
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
发表日期: 2015-06-15
DOI: 10.1002/anie.201502278
卷: 54, 期:25, 页:7405-7409
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Diaryliodonium salts play an increasingly important role as an aryl source. Reported is the first synthesis of diaryliodoniums by rhodium(III)-catalyzed C-H hyperiodination of electron-poor arenes under chelation assistance. This C-I coupling reaction occurred at room temperature with high regio-selectivity and functional-group compatibility. Subsequent diversified nucleophilic functionalization of a diarylio-donium allowed facile construction of C-C, C-N, C-O, C-S, C-P and C-Br bonds, and in all cases the initial functionalization occurred at the arene containing the chelating-group.
关键词[WOS]: ONE-POT SYNTHESIS ;  ROOM-TEMPERATURE ;  UNSYMMETRICAL LAMBDA(3)-IODANES ;  CATALYZED FLUORINATION ;  CHELATION-ASSISTANCE ;  POLYVALENT IODINE ;  ARYLBORONIC ACIDS ;  COUPLING REACTION ;  BOND ACTIVATION ;  IODONIUM SALTS
语种: 英语
WOS记录号: WOS:000356390300035
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146336
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Taiyuan Inst Technol, Dept Chem & Chem Engn, Taiyuan 030008, Peoples R China

Recommended Citation:
Xie, Fang,Zhang, Zhipeng,Yu, Xinzhang,et al. Diaryliodoniums by Rhodium(III)-Catalyzed C-H Activation: Mild Synthesis and Diversified Functionalizations[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(25):7405-7409.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xie, Fang]'s Articles
 [Zhang, Zhipeng]'s Articles
 [Yu, Xinzhang]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xie, Fang]‘s Articles
 [Zhang, Zhipeng]‘s Articles
 [Yu, Xinzhang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace