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Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands
Li, Qing1,2; Hou, Chuan-Jin1,2; Liu, Yan-Jun1; Yang, Rui-Feng1; Hu, Xiang-Ping2
刊名TETRAHEDRON-ASYMMETRY
2015-07-15
DOI10.1016/j.tetasy.2015.05.007
26期:12-13页:617-622
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]CATALYZED ENANTIOSELECTIVE HYDROGENATION ; HYDROXY PHOSPHONATES ; BETA-KETOESTERS ; AL(SALALEN) COMPLEX ; DIPHOSPHINE LIGANDS ; KINETIC RESOLUTION ; N-ARYLIMINES ; HYDROPHOSPHONYLATION ; ALDEHYDES ; HYDROXYPHOSPHONATES
英文摘要Rh-catalyzed asymmetric hydrogenation of challenging alpha-keto phosphonates has been developed. With a new chiral phosphine-phosphoramidite ligand, a wide range of alpha-keto phosphonates were hydrogenated to afford the corresponding (R)-alpha-hydroxy phosphonates with moderate to good enantioselectivities (up to 87% ee). (C) 2015 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000356557200004
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146342
专题中国科学院大连化学物理研究所
作者单位1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Li, Qing,Hou, Chuan-Jin,Liu, Yan-Jun,et al. Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands[J]. TETRAHEDRON-ASYMMETRY,2015,26(12-13):617-622.
APA Li, Qing,Hou, Chuan-Jin,Liu, Yan-Jun,Yang, Rui-Feng,&Hu, Xiang-Ping.(2015).Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands.TETRAHEDRON-ASYMMETRY,26(12-13),617-622.
MLA Li, Qing,et al."Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands".TETRAHEDRON-ASYMMETRY 26.12-13(2015):617-622.
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