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题名: Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands
作者: Li, Qing1, 2;  Hou, Chuan-Jin1, 2;  Liu, Yan-Jun1;  Yang, Rui-Feng1;  Hu, Xiang-Ping2
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2015-07-15
DOI: 10.1016/j.tetasy.2015.05.007
卷: 26, 期:12-13, 页:617-622
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Rh-catalyzed asymmetric hydrogenation of challenging alpha-keto phosphonates has been developed. With a new chiral phosphine-phosphoramidite ligand, a wide range of alpha-keto phosphonates were hydrogenated to afford the corresponding (R)-alpha-hydroxy phosphonates with moderate to good enantioselectivities (up to 87% ee). (C) 2015 Elsevier Ltd. All rights reserved.
关键词[WOS]: CATALYZED ENANTIOSELECTIVE HYDROGENATION ;  HYDROXY PHOSPHONATES ;  BETA-KETOESTERS ;  AL(SALALEN) COMPLEX ;  DIPHOSPHINE LIGANDS ;  KINETIC RESOLUTION ;  N-ARYLIMINES ;  HYDROPHOSPHONYLATION ;  ALDEHYDES ;  HYDROXYPHOSPHONATES
语种: 英语
WOS记录号: WOS:000356557200004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146342
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Li, Qing,Hou, Chuan-Jin,Liu, Yan-Jun,et al. Asymmetric hydrogenation of alpha-keto phosphonates with chiral phosphine-phosphoramidite ligands[J]. TETRAHEDRON-ASYMMETRY,2015,26(12-13):617-622.
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