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题名: Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines
作者: Kong, Lingheng1;  Xie, Fang1;  Yu, Songjie1;  Qi, Zisong1;  Li, Xingwei1
关键词: Rhodium(III) ;  Carbon-hydrogen activation ;  Oxygen-atom transfer ;  Nitrogen-aryl nitrones
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2015-07-01
DOI: 10.1016/S1872-2067(15)60866-X
卷: 36, 期:7, 页:925-932
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Rh-catalyzed redox-neutral coupling between N-aryl nitrones and alkynes has been achieved under relatively mild conditions. The reaction proceeded via C-H activation at the N-aryl ring with subsequent O-atom transfer, affording trisubstituted indolines in good chemoselectivity and moderate to good diasteroselectivity. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: C-H ACTIVATION ;  OXIDIZING DIRECTING GROUP ;  QUINOLINE N-OXIDES ;  INTERNAL OXIDANT ;  BOND ACTIVATION ;  REGIOSELECTIVE SYNTHESIS ;  ATOM TRANSFER ;  FUNCTIONALIZATION ;  PYRIDINES ;  STRATEGY
语种: 英语
WOS记录号: WOS:000356911400002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146355
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Kong, Lingheng,Xie, Fang,Yu, Songjie,et al. Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(7):925-932.
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