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Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines
Kong, Lingheng; Xie, Fang; Yu, Songjie; Qi, Zisong; Li, Xingwei
KeywordRhodium(Iii) Carbon-hydrogen Activation Oxygen-atom Transfer Nitrogen-aryl Nitrones
Source PublicationCHINESE JOURNAL OF CATALYSIS
2015-07-01
DOI10.1016/S1872-2067(15)60866-X
Volume36Issue:7Pages:925-932
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordC-H ACTIVATION ; OXIDIZING DIRECTING GROUP ; QUINOLINE N-OXIDES ; INTERNAL OXIDANT ; BOND ACTIVATION ; REGIOSELECTIVE SYNTHESIS ; ATOM TRANSFER ; FUNCTIONALIZATION ; PYRIDINES ; STRATEGY
AbstractRh-catalyzed redox-neutral coupling between N-aryl nitrones and alkynes has been achieved under relatively mild conditions. The reaction proceeded via C-H activation at the N-aryl ring with subsequent O-atom transfer, affording trisubstituted indolines in good chemoselectivity and moderate to good diasteroselectivity. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000356911400002
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146355
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Kong, Lingheng,Xie, Fang,Yu, Songjie,et al. Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(7):925-932.
APA Kong, Lingheng,Xie, Fang,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines.CHINESE JOURNAL OF CATALYSIS,36(7),925-932.
MLA Kong, Lingheng,et al."Rh(III)-catalyzed coupling of nitrones with alkynes for the synthesis of indolines".CHINESE JOURNAL OF CATALYSIS 36.7(2015):925-932.
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