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Synthesis of conjugated microporous polymers for gas storage and selective adsorption
Shi, Qian1; Sun, Hanxue1; Yang, Ruixia2; Zhu, Zhaoqi1; Liang, Weidong1; Tan, Dazhi3; Yang, Baoping1; Li, An1; Deng, Weiqiao2
刊名JOURNAL OF MATERIALS SCIENCE
2015-10-01
DOI10.1007/s10853-015-9191-x
50期:19页:6388-6394
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Multidisciplinary
研究领域[WOS]Materials Science
关键词[WOS]COVALENT ORGANIC FRAMEWORKS ; TRIAZINE-BASED FRAMEWORKS ; HYDROGEN STORAGE ; SURFACE-AREA ; VISIBLE-LIGHT ; MESH FILM ; NETWORKS ; TRANSPORTATION ; MORPHOLOGIES ; ABSORPTION
英文摘要Two novel CMPs networks with (A(4) + B-3) type and (A(4) + B-2) type were synthesized by Pb(II)/Cu(I)-catalyzed Sonogashira-Hagihara cross-coupling polymerization. The resulting CMPs show high thermal stability with a decomposition temperature above 300 degrees C. The CMPs exhibit high specific surface areas up to 788 m(2) g(-1). Using them as porous platforms, the CO2 adsorption of CMPs was investigated. Meanwhile, the synthesized CMPs show surface superhydrophobicity with water contact angle about 157 degrees due to the microporous morphological structures and the strongly hydrophobic chemical compositions. The organic liquid uptake of CMPs samples was measured up to 1522 wt% for a variety of organic solvents. Furthermore, simply coating of the resulting CMPs on the stainless steel grid enables the wettability of grid changing from hydrophilicity to superhydrophobicity and superoleophilicity, which makes them potential candidates for selective adsorption of oils and organics from water.
语种英语
WOS记录号WOS:000358149600015
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146403
专题中国科学院大连化学物理研究所
作者单位1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
2.Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
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Shi, Qian,Sun, Hanxue,Yang, Ruixia,et al. Synthesis of conjugated microporous polymers for gas storage and selective adsorption[J]. JOURNAL OF MATERIALS SCIENCE,2015,50(19):6388-6394.
APA Shi, Qian.,Sun, Hanxue.,Yang, Ruixia.,Zhu, Zhaoqi.,Liang, Weidong.,...&Deng, Weiqiao.(2015).Synthesis of conjugated microporous polymers for gas storage and selective adsorption.JOURNAL OF MATERIALS SCIENCE,50(19),6388-6394.
MLA Shi, Qian,et al."Synthesis of conjugated microporous polymers for gas storage and selective adsorption".JOURNAL OF MATERIALS SCIENCE 50.19(2015):6388-6394.
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