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Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes
Zhou, Xukai; Yu, Songjie; Qi, Zisong; Li, Xingwei
关键词Rhodium(Iii) C-h Activation Annulation Oxime Alkyne
刊名SCIENCE CHINA-CHEMISTRY
2015-08-01
DOI10.1007/s11426-015-5408-8
58期:8页:1297-1301
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]C-H ACTIVATION ; POLYMER SOLAR-CELLS ; BOND ACTIVATION ; INTERNAL ALKYNES ; AROMATIC KETIMINES ; INDENE FRAMEWORKS ; DERIVATIVES ; CYCLIZATION ; RUTHENIUM ; FUNCTIONALIZATION
英文摘要Rhodium(III)-catalyzed coupling between ketoximes and alkynes via C-H activation and annulation typically followed the [4+2] selectivity to afford isoquinolines. By designing alkynes bearing a highly electron-withdrawing group and under substrate control, we have successfully switched the selectivity of the coupling between oximes and alkynes to the alternative [3+2] annulation, leading to the efficient synthesis of indenamines. This process features good regioselectivity for both substrates, high efficiency, broad substrate scope, and excellent functional group tolerance.
语种英语
WOS记录号WOS:000358605500009
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146414
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Zhou, Xukai,Yu, Songjie,Qi, Zisong,et al. Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes[J]. SCIENCE CHINA-CHEMISTRY,2015,58(8):1297-1301.
APA Zhou, Xukai,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes.SCIENCE CHINA-CHEMISTRY,58(8),1297-1301.
MLA Zhou, Xukai,et al."Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes".SCIENCE CHINA-CHEMISTRY 58.8(2015):1297-1301.
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