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Field Switching Combined with Bradbury-Nielsen Gate for Ion Mobility Spectrometry
Chen, Chuang1; Tabrizchi, Mahmoud2; Wang, Weiguo1; Li, Haiyang1
Source PublicationANALYTICAL CHEMISTRY
2015-08-04
DOI10.1021/acs.analchem.5b01737
Volume87Issue:15Pages:7925-7930
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical
WOS Research AreaChemistry
WOS KeywordRESOLUTION ; DESIGN
AbstractBradbury-Nielsen gate (BNG) is commonly used in ion mobility spectrometers. It, however, transmits only a small fraction of the ions into the drift region, typically 1%. In contrast, all ions in the ionization chamber could be efficiently compressed into the drift region by the field switching gate (FSG). We report in this paper on the simultaneous use of BNG and field switching (FS) to enhance ion utilization of the BNG. In this technique, the FS collects the ions existing in the region between the FS electrode and the BNG and drives them quickly, going through the BNG in the period of gate opening. The BNG acts as the retarding field in the reported FSG to stop ions from diffusing into the drift region in the period of gate closing. Using this technique, an increase of at least 10-fold in the ion peak height without any loss of resolution is achieved for acetone compared with the BNG-only approach at a gate pulse width of 150 mu s, and an even larger improvement factor of 21 is achieved for heavier DMMP dimer ions. This technique can be adapted to the current BNG-based ion mobility instruments to significantly enhance their sensitivity without any modification of the drift tube hardware.
Language英语
WOS IDWOS:000359277900060
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146458
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
Recommended Citation
GB/T 7714
Chen, Chuang,Tabrizchi, Mahmoud,Wang, Weiguo,et al. Field Switching Combined with Bradbury-Nielsen Gate for Ion Mobility Spectrometry[J]. ANALYTICAL CHEMISTRY,2015,87(15):7925-7930.
APA Chen, Chuang,Tabrizchi, Mahmoud,Wang, Weiguo,&Li, Haiyang.(2015).Field Switching Combined with Bradbury-Nielsen Gate for Ion Mobility Spectrometry.ANALYTICAL CHEMISTRY,87(15),7925-7930.
MLA Chen, Chuang,et al."Field Switching Combined with Bradbury-Nielsen Gate for Ion Mobility Spectrometry".ANALYTICAL CHEMISTRY 87.15(2015):7925-7930.
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