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The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4
Wang, Han1,2; Cao, Hujun1; Wu, Guotao1; He, Teng1; Chen, Ping1
关键词Hydrogen Storage Amide-hydride System Sorption Kinetics Li2bnh6
刊名ENERGIES
2015-07-01
DOI10.3390/en8076898
8期:7页:6898-6909
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Energy & Fuels
研究领域[WOS]Energy & Fuels
关键词[WOS]MG-N-H ; DESORPTION PROPERTIES ; HYDRIDE SYSTEM ; LIBH4 ; COMPLEX ; MG(BH4)(2) ; LINH2-MGH2 ; KINETICS ; IMIDES ; LIH
英文摘要2Mg(NH2)(2)-3LiH-LiBH4 composite exhibits an improved kinetic and thermodynamic properties in hydrogen storage in comparison with 2Mg(NH2)(2)-3LiH. The peak temperature of hydrogen desorption drops about 10 K and the peak width shrinks about 50 K compared with the neat 2Mg(NH2)(2)-3LiH. Its isothermal dehydrogenation and re-hydrogenation rates are respectively 2 times and 18 times as fast as those of 2Mg(NH2)(2)-3LiH. A slope desorption region with higher equilibrium pressure is observed. By means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses, the existence of Li2BNH6 is identified and its roles in kinetic and thermodynamic enhancement are discussed.
语种英语
WOS记录号WOS:000359897800034
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146478
专题中国科学院大连化学物理研究所
作者单位1.Dalian Inst Chem Phys, Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Wang, Han,Cao, Hujun,Wu, Guotao,et al. The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4[J]. ENERGIES,2015,8(7):6898-6909.
APA Wang, Han,Cao, Hujun,Wu, Guotao,He, Teng,&Chen, Ping.(2015).The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4.ENERGIES,8(7),6898-6909.
MLA Wang, Han,et al."The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4".ENERGIES 8.7(2015):6898-6909.
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