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题名: Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation
作者: Wang, Qiang1;  Xie, Fang1;  Li, Xingwei1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2015-08-21
DOI: 10.1021/acs.joc.5b00940
卷: 80, 期:16, 页:8361-8366
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Cp*Rh(III) complexes have been applied as efficient catalysts for the C-H activation and trifluoromethylthiolation of indoles functionalized with a heterocycle. With N-trifluoromethylthiosaccharin being an electrophilic SCF3 reagent, this C-S coupling occurred selectively at the 2-position with good functional group tolerance.
关键词[WOS]: BOND ACTIVATION ;  ELECTROPHILIC TRIFLUOROMETHYLTHIOLATION ;  MEDICINAL CHEMISTRY ;  CATALYZED TRIFLUOROMETHYLTHIOLATION ;  NUCLEOPHILIC TRIFLUOROMETHYLATION ;  FLUORINATED ETHERS ;  CARBONYL-COMPOUNDS ;  INTERNAL ALKYNES ;  BORONIC ACIDS ;  SULFIDES
语种: 英语
WOS记录号: WOS:000360103000056
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146503
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Qiang,Xie, Fang,Li, Xingwei. Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(16):8361-8366.
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