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Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation
Wang, Qiang; Xie, Fang; Li, Xingwei
刊名JOURNAL OF ORGANIC CHEMISTRY
2015-08-21
DOI10.1021/acs.joc.5b00940
80期:16页:8361-8366
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]BOND ACTIVATION ; ELECTROPHILIC TRIFLUOROMETHYLTHIOLATION ; MEDICINAL CHEMISTRY ; CATALYZED TRIFLUOROMETHYLTHIOLATION ; NUCLEOPHILIC TRIFLUOROMETHYLATION ; FLUORINATED ETHERS ; CARBONYL-COMPOUNDS ; INTERNAL ALKYNES ; BORONIC ACIDS ; SULFIDES
英文摘要Cp*Rh(III) complexes have been applied as efficient catalysts for the C-H activation and trifluoromethylthiolation of indoles functionalized with a heterocycle. With N-trifluoromethylthiosaccharin being an electrophilic SCF3 reagent, this C-S coupling occurred selectively at the 2-position with good functional group tolerance.
语种英语
WOS记录号WOS:000360103000056
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146503
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Wang, Qiang,Xie, Fang,Li, Xingwei. Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation[J]. JOURNAL OF ORGANIC CHEMISTRY,2015,80(16):8361-8366.
APA Wang, Qiang,Xie, Fang,&Li, Xingwei.(2015).Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation.JOURNAL OF ORGANIC CHEMISTRY,80(16),8361-8366.
MLA Wang, Qiang,et al."Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation".JOURNAL OF ORGANIC CHEMISTRY 80.16(2015):8361-8366.
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