中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Porous carbon in catalytic transformation of cellulose
作者: Zhao, Xiaochen1;  Xu, Jinming1;  Wang, Aiqin1;  Zhang, Tao1
关键词: Biomass conversion ;  Catalysis ;  Porous carbon ;  Activated carbon ;  Mesoporous carbon ;  Cellulose
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2015-09-01
DOI: 10.1016/S1872-2067(15)60942-1
卷: 36, 期:9, 页:1419-1427
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The application of porous carbon in catalytic transformation of cellulose has received considerable interest owing to increasing energy and environmental pressures. In this mini-review, we first outline the featured properties of porous carbon in catalytic cellulose transformation in terms of porosities and surface functionalities. An interconnected hierarchical structure and enrichment of mesopores are highly desired for reactant, intermediate, and product diffusion; while hydrophilic surfaces are favored in aqueous phase transformation and certain acidic oxygen functionalities play a role of acid sites as well as enhancing the adsorption of feedstock via 1,4-glycosidic bonds. We then summarize specific reactions in cellulose transformation in the order of hydrolysis and hydrolytic hydrogenation. In the hydrolysis of cellulose, porous carbon is generally used as a solid acid by taking advantage of its enriched oxygen functionalities, while in the hydrolytic hydrogenation, carbon serves as the support of bifunctional catalysts with active acidic sites. Finally, the synthesis and potential application of specific novel porous carbon materials, such as heteroatom-modified porous carbon and mesoporous carbon composites, are highlighted. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: SUPPORTED RUTHENIUM CATALYSTS ;  ORDERED MESOPOROUS CARBONS ;  ETHYLENE-GLYCOL ;  HYDROLYTIC HYDROGENATION ;  AMORPHOUS-CARBON ;  SUGAR ALCOHOLS ;  AQUEOUS-PHASE ;  DOPED CARBON ;  SOLID ACID ;  CONVERSION
语种: 英语
WOS记录号: WOS:000361084300004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146520
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,et al. Porous carbon in catalytic transformation of cellulose[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1419-1427.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhao, Xiaochen]'s Articles
 [Xu, Jinming]'s Articles
 [Wang, Aiqin]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhao, Xiaochen]‘s Articles
 [Xu, Jinming]‘s Articles
 [Wang, Aiqin]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace