DICP OpenIR
Porous carbon in catalytic transformation of cellulose
Zhao, Xiaochen; Xu, Jinming; Wang, Aiqin; Zhang, Tao
KeywordBiomass Conversion Catalysis Porous Carbon Activated Carbon Mesoporous Carbon Cellulose
Source PublicationCHINESE JOURNAL OF CATALYSIS
2015-09-01
DOI10.1016/S1872-2067(15)60942-1
Volume36Issue:9Pages:1419-1427
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordSUPPORTED RUTHENIUM CATALYSTS ; ORDERED MESOPOROUS CARBONS ; ETHYLENE-GLYCOL ; HYDROLYTIC HYDROGENATION ; AMORPHOUS-CARBON ; SUGAR ALCOHOLS ; AQUEOUS-PHASE ; DOPED CARBON ; SOLID ACID ; CONVERSION
AbstractThe application of porous carbon in catalytic transformation of cellulose has received considerable interest owing to increasing energy and environmental pressures. In this mini-review, we first outline the featured properties of porous carbon in catalytic cellulose transformation in terms of porosities and surface functionalities. An interconnected hierarchical structure and enrichment of mesopores are highly desired for reactant, intermediate, and product diffusion; while hydrophilic surfaces are favored in aqueous phase transformation and certain acidic oxygen functionalities play a role of acid sites as well as enhancing the adsorption of feedstock via 1,4-glycosidic bonds. We then summarize specific reactions in cellulose transformation in the order of hydrolysis and hydrolytic hydrogenation. In the hydrolysis of cellulose, porous carbon is generally used as a solid acid by taking advantage of its enriched oxygen functionalities, while in the hydrolytic hydrogenation, carbon serves as the support of bifunctional catalysts with active acidic sites. Finally, the synthesis and potential application of specific novel porous carbon materials, such as heteroatom-modified porous carbon and mesoporous carbon composites, are highlighted. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000361084300004
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146520
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,et al. Porous carbon in catalytic transformation of cellulose[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1419-1427.
APA Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,&Zhang, Tao.(2015).Porous carbon in catalytic transformation of cellulose.CHINESE JOURNAL OF CATALYSIS,36(9),1419-1427.
MLA Zhao, Xiaochen,et al."Porous carbon in catalytic transformation of cellulose".CHINESE JOURNAL OF CATALYSIS 36.9(2015):1419-1427.
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