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Porous carbon in catalytic transformation of cellulose
Zhao, Xiaochen; Xu, Jinming; Wang, Aiqin; Zhang, Tao
关键词Biomass Conversion Catalysis Porous Carbon Activated Carbon Mesoporous Carbon Cellulose
刊名CHINESE JOURNAL OF CATALYSIS
2015-09-01
DOI10.1016/S1872-2067(15)60942-1
36期:9页:1419-1427
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]SUPPORTED RUTHENIUM CATALYSTS ; ORDERED MESOPOROUS CARBONS ; ETHYLENE-GLYCOL ; HYDROLYTIC HYDROGENATION ; AMORPHOUS-CARBON ; SUGAR ALCOHOLS ; AQUEOUS-PHASE ; DOPED CARBON ; SOLID ACID ; CONVERSION
英文摘要The application of porous carbon in catalytic transformation of cellulose has received considerable interest owing to increasing energy and environmental pressures. In this mini-review, we first outline the featured properties of porous carbon in catalytic cellulose transformation in terms of porosities and surface functionalities. An interconnected hierarchical structure and enrichment of mesopores are highly desired for reactant, intermediate, and product diffusion; while hydrophilic surfaces are favored in aqueous phase transformation and certain acidic oxygen functionalities play a role of acid sites as well as enhancing the adsorption of feedstock via 1,4-glycosidic bonds. We then summarize specific reactions in cellulose transformation in the order of hydrolysis and hydrolytic hydrogenation. In the hydrolysis of cellulose, porous carbon is generally used as a solid acid by taking advantage of its enriched oxygen functionalities, while in the hydrolytic hydrogenation, carbon serves as the support of bifunctional catalysts with active acidic sites. Finally, the synthesis and potential application of specific novel porous carbon materials, such as heteroatom-modified porous carbon and mesoporous carbon composites, are highlighted. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000361084300004
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146520
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
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GB/T 7714
Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,et al. Porous carbon in catalytic transformation of cellulose[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1419-1427.
APA Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,&Zhang, Tao.(2015).Porous carbon in catalytic transformation of cellulose.CHINESE JOURNAL OF CATALYSIS,36(9),1419-1427.
MLA Zhao, Xiaochen,et al."Porous carbon in catalytic transformation of cellulose".CHINESE JOURNAL OF CATALYSIS 36.9(2015):1419-1427.
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