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An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines
Zhang, Zhixin2; Wang, Yehong1,2; Wang, Min2; Lu, Jianmin2; Li, Lihua2; Zhang, Zhe2; Li, Mingrun2; Jiang, Jingyang1; Wang, Feng2
关键词Ceria Crystal Plane Effect Oxidative Coupling Imine Defect Site
刊名CHINESE JOURNAL OF CATALYSIS
2015-09-01
DOI10.1016/S1872-2067(15)60869-5
36期:9页:1623-1630
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]ONE-POT SYNTHESIS ; SELECTIVE SYNTHESIS ; GOLD NANOPARTICLES ; RAMAN-SPECTROSCOPY ; TANDEM SYNTHESIS ; LOW-TEMPERATURE ; CERIA ; CATALYST ; OXYGEN ; SECONDARY
英文摘要We herein report the effects of CeO2 crystal planes on the oxidative coupling of alcohols and amines to form imines. CeO2 exhibits significant catalytic activity under mild reaction conditions (60 degrees C) during the synthesis of 13 different imines, giving >89% conversions and >90% selectivities. The crystal planes of CeO2 greatly affect the catalytic performance. Among the crystal planes investigated (the (110), (100) and (111) planes), the (110) plane shows the strongest redox ability and thus the best catalytic activity, generating a 97% yield of the imine at 60 degrees C in 2 h, because it contains the highest concentration of oxygen vacancies. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000361084300024
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146524
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Coll Chem, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
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Zhang, Zhixin,Wang, Yehong,Wang, Min,et al. An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1623-1630.
APA Zhang, Zhixin.,Wang, Yehong.,Wang, Min.,Lu, Jianmin.,Li, Lihua.,...&Wang, Feng.(2015).An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines.CHINESE JOURNAL OF CATALYSIS,36(9),1623-1630.
MLA Zhang, Zhixin,et al."An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and amines".CHINESE JOURNAL OF CATALYSIS 36.9(2015):1623-1630.
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