中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system
作者: Li, Changzhi1;  Cai, Haile1;  Zhang, Bo1;  Li, Weizhen1;  Pei, Guangxian1, 2;  Dai, Tao1, 2;  Wang, Aiqin1, 3;  Zhang, Tao1, 3
关键词: Biomass ;  Ionic liquids ;  2,5-Dimethylfuran ;  2,5-Dimethyltetrahydrofuran ;  5-Hydroxylmethylfufural ;  Fructose ;  Biofuel
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2015-09-01
DOI: 10.1016/S1872-2067(15)60927-5
卷: 36, 期:9, 页:1638-1646
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The one-pot catalytic transformation of biomass to useful products is desirable for saving cost and time. The integration of the various reaction steps need to address the presence of incompatible reaction conditions and numerous side reactions. We report a novel process for the one-pot production of furan-based fuels, 2,5-dimethylfuran (DMF) and 2,5-dihmethyltetrahydrofuran (DMTF), from fructose by optimizing the synergic effect of an ionic liquid promoted Ru/C catalyst and the solvent effect. The dehydration of fructose and subsequent in situ hydrodeoxygenation of HMF to DMF and DMTF on Ru/C were enhanced by the use of an ionic liquid and a biphasic [BMIm]Cl/THF solvent. Elemental analysis, X-ray Photoelectron Spectroscopy, Raman spectroscopy and H2-temperature programmed reduction-mass spectroscopy characterization showed that the ionic liquid modified the electronic density of the Ru species to favor HMF in situ hydrodeoxygenation. Moreover, THF served as a reaction-extraction solvent that extracted DMF and DMTF from the reaction layer to avoid further side reactions. A rational design that gave enhancement of the catalytic performance and product protection provides a promising strategy for the one-pot conversion of biomass to desired fuels. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: EFFICIENT PRODUCTION ;  ETHYLENE-GLYCOL ;  BIOMASS ;  CHEMICALS ;  CELLULOSE ;  2,5-DIMETHYLFURAN ;  CONVERSION ;  CATALYSTS ;  INSIGHT ;  TRANSFORMATION
语种: 英语
WOS记录号: WOS:000361084300026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146526
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Li, Changzhi,Cai, Haile,Zhang, Bo,et al. Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1638-1646.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, Changzhi]'s Articles
 [Cai, Haile]'s Articles
 [Zhang, Bo]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, Changzhi]‘s Articles
 [Cai, Haile]‘s Articles
 [Zhang, Bo]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace