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Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system
Li, Changzhi1; Cai, Haile1; Zhang, Bo1; Li, Weizhen1; Pei, Guangxian1,2; Dai, Tao1,2; Wang, Aiqin1,3; Zhang, Tao1,3
KeywordBiomass Ionic Liquids 2 5-hydroxylmethylfufural 5-dimethylfuran 2 Fructose 5-dimethyltetrahydrofuran Biofuel
Source PublicationCHINESE JOURNAL OF CATALYSIS
2015-09-01
DOI10.1016/S1872-2067(15)60927-5
Volume36Issue:9Pages:1638-1646
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordEFFICIENT PRODUCTION ; ETHYLENE-GLYCOL ; BIOMASS ; CHEMICALS ; CELLULOSE ; 2,5-DIMETHYLFURAN ; CONVERSION ; CATALYSTS ; INSIGHT ; TRANSFORMATION
AbstractThe one-pot catalytic transformation of biomass to useful products is desirable for saving cost and time. The integration of the various reaction steps need to address the presence of incompatible reaction conditions and numerous side reactions. We report a novel process for the one-pot production of furan-based fuels, 2,5-dimethylfuran (DMF) and 2,5-dihmethyltetrahydrofuran (DMTF), from fructose by optimizing the synergic effect of an ionic liquid promoted Ru/C catalyst and the solvent effect. The dehydration of fructose and subsequent in situ hydrodeoxygenation of HMF to DMF and DMTF on Ru/C were enhanced by the use of an ionic liquid and a biphasic [BMIm]Cl/THF solvent. Elemental analysis, X-ray Photoelectron Spectroscopy, Raman spectroscopy and H2-temperature programmed reduction-mass spectroscopy characterization showed that the ionic liquid modified the electronic density of the Ru species to favor HMF in situ hydrodeoxygenation. Moreover, THF served as a reaction-extraction solvent that extracted DMF and DMTF from the reaction layer to avoid further side reactions. A rational design that gave enhancement of the catalytic performance and product protection provides a promising strategy for the one-pot conversion of biomass to desired fuels. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000361084300026
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146526
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Li, Changzhi,Cai, Haile,Zhang, Bo,et al. Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1638-1646.
APA Li, Changzhi.,Cai, Haile.,Zhang, Bo.,Li, Weizhen.,Pei, Guangxian.,...&Zhang, Tao.(2015).Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system.CHINESE JOURNAL OF CATALYSIS,36(9),1638-1646.
MLA Li, Changzhi,et al."Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system".CHINESE JOURNAL OF CATALYSIS 36.9(2015):1638-1646.
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