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题名: Synthesis of Chiral Trifluoromethyl-Substituted Hydrazines via Pd-Catalyzed Asymmetric Hydrogenation and Reductive Amination
作者: Chen, Zhang-Pei1;  Hu, Shu-Bo1;  Zhou, Ji1;  Zhou, Yong-Gui1, 2
关键词: palladium ;  asymmetric hydrogenation ;  reductive amination ;  trifluoromethylated hydrazines ;  Bronsted acid
刊名: ACS CATALYSIS
发表日期: 2015-10-01
DOI: 10.1021/acscatal.5b01641
卷: 5, 期:10, 页:6086-6089
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: An efficient approach toward the synthesis of cyclic and linear chiral trifluoromethyl substituted hydrazines was developed by Pd-catalyzed asymmetric hydrogenation of both N-acyl and N-aryl hydrazones in excellent yields and up to 97% ee. A successful reductive amination between trifluormethyl substituted ketones and hydrazines was also achieved.
关键词[WOS]: PARTIALLY-MODIFIED RETRO ;  ENANTIOSELECTIVE HYDROGENATION ;  PERFLUOROALKYLATION REACTIONS ;  MEDICINAL CHEMISTRY ;  FACILE ACCESS ;  KETONES ;  AMINES ;  ACID ;  FLUORINATION ;  PYRAZOLIDINE
语种: 英语
WOS记录号: WOS:000362391500046
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146565
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Chen, Zhang-Pei,Hu, Shu-Bo,Zhou, Ji,et al. Synthesis of Chiral Trifluoromethyl-Substituted Hydrazines via Pd-Catalyzed Asymmetric Hydrogenation and Reductive Amination[J]. ACS CATALYSIS,2015,5(10):6086-6089.
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