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Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines
Chen, Bo1,2; Wang, Lianyue1; Gao, Shuang1
关键词Aerobic Oxidation Alcohols Amities Catalysis Imines
刊名ACS CATALYSIS
2015-10-01
DOI10.1021/acscatal.5b01479
5期:10页:5851-5876
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ONE-POT SYNTHESIS ; SOLVENT-FREE CONDITIONS ; SUPPORTED GOLD NANOPARTICLES ; CATALYZED DIRECT SYNTHESIS ; METAL-ORGANIC FRAMEWORKS ; HIGHLY EFFICIENT ; SECONDARY-AMINES ; SELECTIVE OXIDATION ; AMBIENT CONDITIONS ; TANDEM SYNTHESIS
英文摘要Imines as valuable intermediates are widely applied in pharmaceutical syntheses and organic transformation. However, the traditional imine synthesis involves unstable aldehydes, dehydrating agents, and Lewis acid catalysts. The topic of this review is focused on three new approaches, namely, the cross-coupling of alcohols with amines, the self-coupling of primarily amines, and the oxidative dehydrogenation of secondary amines, utilizing much more readily available starting materials and green oxidant (O-2/air) to furnish the imine products. The related catalysts are classified into metal, metal-free, photo-, and bioinspired catalysts. Particular emphasis is placed on the high-active, low-cost, and versatile catalysts; key factors that affect the catalytic activity and reaction mechanisms are also highlighted.
语种英语
WOS记录号WOS:000362391500022
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被引频次:114[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/146571
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Chen, Bo,Wang, Lianyue,Gao, Shuang. Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines[J]. ACS CATALYSIS,2015,5(10):5851-5876.
APA Chen, Bo,Wang, Lianyue,&Gao, Shuang.(2015).Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines.ACS CATALYSIS,5(10),5851-5876.
MLA Chen, Bo,et al."Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines".ACS CATALYSIS 5.10(2015):5851-5876.
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