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题名: Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines
作者: Chen, Bo1, 2;  Wang, Lianyue1;  Gao, Shuang1
关键词: aerobic oxidation ;  alcohols ;  amities ;  catalysis ;  imines
刊名: ACS CATALYSIS
发表日期: 2015-10-01
DOI: 10.1021/acscatal.5b01479
卷: 5, 期:10, 页:5851-5876
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Imines as valuable intermediates are widely applied in pharmaceutical syntheses and organic transformation. However, the traditional imine synthesis involves unstable aldehydes, dehydrating agents, and Lewis acid catalysts. The topic of this review is focused on three new approaches, namely, the cross-coupling of alcohols with amines, the self-coupling of primarily amines, and the oxidative dehydrogenation of secondary amines, utilizing much more readily available starting materials and green oxidant (O-2/air) to furnish the imine products. The related catalysts are classified into metal, metal-free, photo-, and bioinspired catalysts. Particular emphasis is placed on the high-active, low-cost, and versatile catalysts; key factors that affect the catalytic activity and reaction mechanisms are also highlighted.
关键词[WOS]: ONE-POT SYNTHESIS ;  SOLVENT-FREE CONDITIONS ;  SUPPORTED GOLD NANOPARTICLES ;  CATALYZED DIRECT SYNTHESIS ;  METAL-ORGANIC FRAMEWORKS ;  HIGHLY EFFICIENT ;  SECONDARY-AMINES ;  SELECTIVE OXIDATION ;  AMBIENT CONDITIONS ;  TANDEM SYNTHESIS
语种: 英语
WOS记录号: WOS:000362391500022
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/146571
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Chen, Bo,Wang, Lianyue,Gao, Shuang. Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines[J]. ACS CATALYSIS,2015,5(10):5851-5876.
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