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Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines
Chen, Bo1,2; Wang, Lianyue1; Gao, Shuang1
KeywordAerobic Oxidation Alcohols Amities Catalysis Imines
Source PublicationACS CATALYSIS
2015-10-01
DOI10.1021/acscatal.5b01479
Volume5Issue:10Pages:5851-5876
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordONE-POT SYNTHESIS ; SOLVENT-FREE CONDITIONS ; SUPPORTED GOLD NANOPARTICLES ; CATALYZED DIRECT SYNTHESIS ; METAL-ORGANIC FRAMEWORKS ; HIGHLY EFFICIENT ; SECONDARY-AMINES ; SELECTIVE OXIDATION ; AMBIENT CONDITIONS ; TANDEM SYNTHESIS
AbstractImines as valuable intermediates are widely applied in pharmaceutical syntheses and organic transformation. However, the traditional imine synthesis involves unstable aldehydes, dehydrating agents, and Lewis acid catalysts. The topic of this review is focused on three new approaches, namely, the cross-coupling of alcohols with amines, the self-coupling of primarily amines, and the oxidative dehydrogenation of secondary amines, utilizing much more readily available starting materials and green oxidant (O-2/air) to furnish the imine products. The related catalysts are classified into metal, metal-free, photo-, and bioinspired catalysts. Particular emphasis is placed on the high-active, low-cost, and versatile catalysts; key factors that affect the catalytic activity and reaction mechanisms are also highlighted.
Language英语
WOS IDWOS:000362391500022
Citation statistics
Cited Times:148[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/146571
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Chen, Bo,Wang, Lianyue,Gao, Shuang. Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines[J]. ACS CATALYSIS,2015,5(10):5851-5876.
APA Chen, Bo,Wang, Lianyue,&Gao, Shuang.(2015).Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines.ACS CATALYSIS,5(10),5851-5876.
MLA Chen, Bo,et al."Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines".ACS CATALYSIS 5.10(2015):5851-5876.
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