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Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks
Yang, Shifeng1,2; Ren, Wenfeng1; Chen, Jian1
关键词Cathode Materials Lini0.5mn1.5o4 Metal-organic Frameworks Pta
刊名IONICS
2017-11-01
DOI10.1007/s11581-017-2102-1
23期:11页:2969-2980
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter
研究领域[WOS]Chemistry ; Electrochemistry ; Physics
关键词[WOS]LITHIUM-ION BATTERIES ; LONG-CYCLE-LIFE ; HIGH-POWER ; ELECTROCHEMICAL PERFORMANCES ; SURFACE MODIFICATION ; ELECTRODE MATERIAL ; CAPACITY ; SUPERCAPACITORS ; NANOSTRUCTURES ; LIMN1.5NI0.5O4
英文摘要Various synthesis methods have been developed to synthesize mixed metal oxide cathode materials, whereas the scale-up production is hindered by issues of complicated processes, high cost, and inhomogeneity of the prepared materials. Herein, a facile, low-cost, and scalable synthesis route using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks (PTA-based MOFs) as precursors has been explored to synthesize LiNi0.5Mn1.5O4 materials with homogeneity and high crystallinity. Bimetallic PTA-based MOFs were first prepared by the reaction of metal acetates and PTA in the aqueous solution at room temperature. After thermal treatment of PTA-based MOFs, bimetal oxides (Ni-Mn-O) with the inherited morphology of porous nanoplates consisting of 20-30-nm nanoparticles were obtained. The LiNi0.5Mn1.5O4 materials prepared by calcination of Ni-Mn-O with lithium salts exhibit excellent rate capability and cycling performance, delivering a specific capacity of 115.9 mAh g(-1) at 20 C and retaining 83.8% after 500 cycles. This work opens a new way for fabrication of PTA-based MOFs and mixed metal oxides as cathode materials for lithium-ion batteries.
语种英语
WOS记录号WOS:000414026000003
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149675
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Adv Rechargeable Battery Lab, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Yang, Shifeng,Ren, Wenfeng,Chen, Jian. Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks[J]. IONICS,2017,23(11):2969-2980.
APA Yang, Shifeng,Ren, Wenfeng,&Chen, Jian.(2017).Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks.IONICS,23(11),2969-2980.
MLA Yang, Shifeng,et al."Facile synthesis of spinel LiNi0.5Mn1.5O4 cathode materials using M-2(OH)(2)(C8H4O4)-class metal-organic frameworks".IONICS 23.11(2017):2969-2980.
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