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Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones
Xia, Jintao1,2; Kong, Lingheng1,2; Zhou, Xukai1,2; Zheng, Guangfan1; Li, Xingwei1
刊名ORGANIC LETTERS
2017-11-03
DOI10.1021/acs.orglett.7b02983
19期:21页:5972-5975
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PALLADIUM-CATALYZED HYDROCARBOXYLATION ; CARBON-DIOXIDE ; FORMIC-ACID ; REGIOSELECTIVE HYDROCARBOXYLATION ; RHODIUM CATALYSIS ; CARBOXYLIC-ACIDS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; ARENES ; ALKYNES
英文摘要An efficient synthesis of disubstituted acrylic acids has been realized via Rh(III)-catalyzed C-H activation of (hetero)arenes and coupling with four-membered methyleneoxetanones under redox-neutral conditions. In most cases, the reactions are silver-free, and the products are exclusively E-selective with a broad substrate scope. The transformation proceeds via ortho C-H activation followed by selective olefin insertion and beta-oxygen elimination.
语种英语
WOS记录号WOS:000414723900066
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149683
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Xia, Jintao,Kong, Lingheng,Zhou, Xukai,et al. Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones[J]. ORGANIC LETTERS,2017,19(21):5972-5975.
APA Xia, Jintao,Kong, Lingheng,Zhou, Xukai,Zheng, Guangfan,&Li, Xingwei.(2017).Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones.ORGANIC LETTERS,19(21),5972-5975.
MLA Xia, Jintao,et al."Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones".ORGANIC LETTERS 19.21(2017):5972-5975.
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