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Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones
Xia, Jintao1,2; Kong, Lingheng1,2; Zhou, Xukai1,2; Zheng, Guangfan1; Li, Xingwei1
Source PublicationORGANIC LETTERS
2017-11-03
DOI10.1021/acs.orglett.7b02983
Volume19Issue:21Pages:5972-5975
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPALLADIUM-CATALYZED HYDROCARBOXYLATION ; CARBON-DIOXIDE ; FORMIC-ACID ; REGIOSELECTIVE HYDROCARBOXYLATION ; RHODIUM CATALYSIS ; CARBOXYLIC-ACIDS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; ARENES ; ALKYNES
AbstractAn efficient synthesis of disubstituted acrylic acids has been realized via Rh(III)-catalyzed C-H activation of (hetero)arenes and coupling with four-membered methyleneoxetanones under redox-neutral conditions. In most cases, the reactions are silver-free, and the products are exclusively E-selective with a broad substrate scope. The transformation proceeds via ortho C-H activation followed by selective olefin insertion and beta-oxygen elimination.
Language英语
WOS IDWOS:000414723900066
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149683
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xia, Jintao,Kong, Lingheng,Zhou, Xukai,et al. Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones[J]. ORGANIC LETTERS,2017,19(21):5972-5975.
APA Xia, Jintao,Kong, Lingheng,Zhou, Xukai,Zheng, Guangfan,&Li, Xingwei.(2017).Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones.ORGANIC LETTERS,19(21),5972-5975.
MLA Xia, Jintao,et al."Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C-H Allylation of (Hetero)Arenes with Methyleneoxetanones".ORGANIC LETTERS 19.21(2017):5972-5975.
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