中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Knitting Aryl Network Polymers-Incorporated Ag Nanoparticles: A Mild and Efficient Catalyst for the Fixation of CO2 as Carboxylic Acid
作者: Wu, Zhilian1, 2, 4;  Liu, Qinggang2;  Yang, Xiaofeng2;  Ye, Xue2;  Duan, Hongmin2;  Zhang, Jian2;  Zhao, Bo3;  Huang, Yanqiang2
关键词: Carbon dioxide ;  Porous organic polymers ;  Heterogeneous catalyst ;  Alkynyl carboxylic acid
刊名: ACS SUSTAINABLE CHEMISTRY & ENGINEERING
发表日期: 2017-11-01
DOI: 10.1021/acssuschemeng.7b02678
卷: 5, 期:11, 页:9634-9639
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A simple and scalable method for synthesizing silver nanoparticles supported on the framework of mesoporous knitting aryl network polymers (KAPs) has been developed. With the benefits from its mesoporous texture and the stabilizing effect of phosphine compounds in the matrix, the silver precursor can be efficiently introduced into the KAPs framework, which results in a nanosize distribution of Ag (ca. 4.1 nm) supported on KAPs (Ag/KAPs-P) with narrow particle size distribution and homogeneous dispersion after simple reduction step. The as-obtained metal small sized Ag/KAPs-P catalyst is particularly active for the direct carboxylation of terminal alkynes with CO2 into carboxylic acid at low temperature and atmospheric pressure. Moreover, this Ag/KAPs-P catalyst also shows high stability under the reaction conditions, and it can be recycled at least five times without significant loss of activity, suggesting its great potential application in the heterogeneous conversion of CO2 into carboxylic acid.
关键词[WOS]: METAL-ORGANIC FRAMEWORKS ;  CARBON-DIOXIDE ;  CHEMOSELECTIVE HYDROGENATION ;  TERMINAL ALKYNES ;  AMBIENT-PRESSURE ;  MICROPOROUS POLYMERS ;  AROMATIC KETONES ;  SELECTIVITY ;  CONVERSION ;  CAPTURE
语种: 英语
WOS记录号: WOS:000414825900013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149686
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, 2 Nengyuan Rd,Wushan St, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, State Key Lab Catalysis, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Global Energy Interconnect Res Inst, State Key Lab Adv Power Transmiss Technol, Beijing 102211, Peoples R China
4.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China

Recommended Citation:
Wu, Zhilian,Liu, Qinggang,Yang, Xiaofeng,et al. Knitting Aryl Network Polymers-Incorporated Ag Nanoparticles: A Mild and Efficient Catalyst for the Fixation of CO2 as Carboxylic Acid[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5(11):9634-9639.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Wu, Zhilian]'s Articles
 [Liu, Qinggang]'s Articles
 [Yang, Xiaofeng]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Wu, Zhilian]‘s Articles
 [Liu, Qinggang]‘s Articles
 [Yang, Xiaofeng]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace