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Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins
Li, Yunyun1,2; Yang, Xifa1,2; Kong, Lingheng1,2; Li, Xingwei1
刊名ORGANIC CHEMISTRY FRONTIERS
2017-11-01
DOI10.1039/c7qo00510e
4期:11页:2114-2118
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CHIRAL 3-SUBSTITUTED INDANONES ; SPONGE TERPIOS-HOSHINOTA ; BOND FUNCTIONALIZATION ; N-HETEROCYCLES ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED ANNULATION ; DIAZO-COMPOUNDS ; ALKYNES ; ALKENES ; DERIVATIVES
英文摘要Phosphonium ylide acts as an efficient bifunctional directing group in Rh(III)-catalyzed C-H activation of arenes and oxidative coupling with activated olefins, leading to facile construction of indanones via a sequence of oxidative olefination and carboannulation. The phosphonium moiety functions as an oxophilic group, and dephosphination triggers a nucleophilic cyclization.
语种英语
WOS记录号WOS:000413826400005
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149693
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Li, Yunyun,Yang, Xifa,Kong, Lingheng,et al. Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2114-2118.
APA Li, Yunyun,Yang, Xifa,Kong, Lingheng,&Li, Xingwei.(2017).Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins.ORGANIC CHEMISTRY FRONTIERS,4(11),2114-2118.
MLA Li, Yunyun,et al."Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins".ORGANIC CHEMISTRY FRONTIERS 4.11(2017):2114-2118.
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