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题名: Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins
作者: Li, Yunyun1, 2;  Yang, Xifa1, 2;  Kong, Lingheng1, 2;  Li, Xingwei1
刊名: ORGANIC CHEMISTRY FRONTIERS
发表日期: 2017-11-01
DOI: 10.1039/c7qo00510e
卷: 4, 期:11, 页:2114-2118
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Phosphonium ylide acts as an efficient bifunctional directing group in Rh(III)-catalyzed C-H activation of arenes and oxidative coupling with activated olefins, leading to facile construction of indanones via a sequence of oxidative olefination and carboannulation. The phosphonium moiety functions as an oxophilic group, and dephosphination triggers a nucleophilic cyclization.
关键词[WOS]: CHIRAL 3-SUBSTITUTED INDANONES ;  SPONGE TERPIOS-HOSHINOTA ;  BOND FUNCTIONALIZATION ;  N-HETEROCYCLES ;  ENANTIOSELECTIVE SYNTHESIS ;  CATALYZED ANNULATION ;  DIAZO-COMPOUNDS ;  ALKYNES ;  ALKENES ;  DERIVATIVES
语种: 英语
WOS记录号: WOS:000413826400005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149756
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Li, Yunyun,Yang, Xifa,Kong, Lingheng,et al. Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2114-2118.
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