DICP OpenIR
Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins
Li, Yunyun1,2; Yang, Xifa1,2; Kong, Lingheng1,2; Li, Xingwei1
Source PublicationORGANIC CHEMISTRY FRONTIERS
2017-11-01
DOI10.1039/c7qo00510e
Volume4Issue:11Pages:2114-2118
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordCHIRAL 3-SUBSTITUTED INDANONES ; SPONGE TERPIOS-HOSHINOTA ; BOND FUNCTIONALIZATION ; N-HETEROCYCLES ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED ANNULATION ; DIAZO-COMPOUNDS ; ALKYNES ; ALKENES ; DERIVATIVES
AbstractPhosphonium ylide acts as an efficient bifunctional directing group in Rh(III)-catalyzed C-H activation of arenes and oxidative coupling with activated olefins, leading to facile construction of indanones via a sequence of oxidative olefination and carboannulation. The phosphonium moiety functions as an oxophilic group, and dephosphination triggers a nucleophilic cyclization.
Language英语
WOS IDWOS:000413826400005
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149756
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Yunyun,Yang, Xifa,Kong, Lingheng,et al. Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2114-2118.
APA Li, Yunyun,Yang, Xifa,Kong, Lingheng,&Li, Xingwei.(2017).Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins.ORGANIC CHEMISTRY FRONTIERS,4(11),2114-2118.
MLA Li, Yunyun,et al."Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins".ORGANIC CHEMISTRY FRONTIERS 4.11(2017):2114-2118.
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