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In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O
Wang, Tianlong1,2; Ma, Hong1; Gao, Jin1; Wang, Xinhong2; Sun, Yuxia1,3; Luo, Yang1,3; Zhang, Shujing1,3; Xu, Jie1
KeywordDual-metal Fabrication Organic-inorganic Hybrids Photocatalysis Zeolitic Imidazolate Frameworks
Source PublicationCHEMISTRY-AN ASIAN JOURNAL
2017-11-02
DOI10.1002/asia.201701189
Volume12Issue:21Pages:2790-2793
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMETAL-ORGANIC FRAMEWORK ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; CORE-SHELL ; THERMAL-CONVERSION ; NANOPOROUS CARBONS ; HIGH-PERFORMANCE ; FACILE SYNTHESIS ; NANOPARTICLES ; SELECTIVITY ; CATALYSIS
AbstractWe successfully fabricate a well-defined inorganic/organic hybrid Cu2O@Cu/Co-ZIF (ZIF = zeolitic imidazolate frameworks) by use of growth of dual-metal Cu/Co-ZIF on the obtained Cu2O hollow spheres. The key point of the strategy is coupling the in situ self-sacrificing template. Cu2O and the coordination of metal ions (Cu+ and Co2+) with 2-methylimidazole. This new hybrid was characterized by powder X-ray diffraction, (scanning) transmission electron microscopy, energy-dispersive spectroscopy mapping, in situ FT-IR spectroscopy, UV/Vis diffuse reflection spectroscopy, N-2 sorption measurements, and electron spin resonance. It was evidenced that Cu/Co-ZIF nanocrystals have been assembled to continuous shells surrounding the Cu2O cores as well as in the voids between layers and inner pores. Cu2O@Cu/Co-ZIF exhibits visible light responsiveness and holds potential as narrow band gap semiconductor and visible photocatalyst.
Language英语
WOS IDWOS:000414338400003
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149771
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Tianlong,Ma, Hong,Gao, Jin,et al. In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(21):2790-2793.
APA Wang, Tianlong.,Ma, Hong.,Gao, Jin.,Wang, Xinhong.,Sun, Yuxia.,...&Xu, Jie.(2017).In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O.CHEMISTRY-AN ASIAN JOURNAL,12(21),2790-2793.
MLA Wang, Tianlong,et al."In Situ Fabrication of Inorganic/Organic Hybrid Based on Cu/Co-ZIF and Cu2O".CHEMISTRY-AN ASIAN JOURNAL 12.21(2017):2790-2793.
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