中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones
作者: Liu, Tingting1, 2;  Chai, Huining1, 2;  Wang, Liandi1;  Yu, Zhengkun1, 3
刊名: ORGANOMETALLICS
发表日期: 2017-08-14
DOI: 10.1021/acs.organomet.7b00356
卷: 36, 期:15, 页:2914-2921
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Dinuclear ruthenium(II)-NNN complexes were efficiently assembled by means of coordinatively unsaturated 16-electron mononuclear ruthenium(II)-pyrazolyl-imidazolyl-pyridine complex and 4,4'-linked bipyridine ligands. The diruthenium(II)-NNN complex assembled through 4,4'-(CH2)(3)-bipyridine exhibited exceptionally high catalytic activity for the transfer hydrogenation (TH) of ketones in refluxing 2-propanol and reached TOF values up to 1.4 x 10(7) h(-1), demonstrating a remarkable cooperative effect from the ruthenium(II)-NNN functionalities.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  PYRAZOLYL-IMIDAZOLYL LIGAND ;  HETEROMETALLIC COMPLEXES ;  METAL-COMPLEXES ;  NNN LIGAND ;  BEARING ;  OXIDATION ;  OXYGEN ;  WATER ;  COOPERATIVITY
语种: 英语
WOS记录号: WOS:000407869100025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149811
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China

Recommended Citation:
Liu, Tingting,Chai, Huining,Wang, Liandi,et al. Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2017,36(15):2914-2921.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Liu, Tingting]'s Articles
 [Chai, Huining]'s Articles
 [Wang, Liandi]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Liu, Tingting]‘s Articles
 [Chai, Huining]‘s Articles
 [Wang, Liandi]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace