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A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition
Hong, Shaojing1,2; Hou, Ming1; Zhang, Hongjie1,2; Jiang, Yongyi1,2; Shao, Zhigang1; Yi, Baolian1
KeywordProton Exchange Membrane Fuel Cell Electrospun Electrode Underpotential Deposition
Source PublicationELECTROCHIMICA ACTA
2017-08-10
DOI10.1016/j.electacta.2017.05.066
Volume245Pages:395-401
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectElectrochemistry
WOS Research AreaElectrochemistry
WOS KeywordOXYGEN REDUCTION REACTION ; SUPPORTED PD NANOPARTICLES ; CORE-SHELL ; MONOLAYER ELECTROCATALYSTS ; O-2 REDUCTION ; CATALYSTS ; CATHODE ; LAYER ; NANOSTRUCTURES ; RESISTANCE
AbstractA novel PEMFC electrode (E-U electrode) with ultralow platinum is prepared by electrospinning and underpotential deposition techniques. The platinum skin (Ptskin) is in situ deposited on the surface of Pd nanoparticle in the electrospun Pd/ C catalyst layer. The energy-dispersive X-ray spectroscopy (EDS) mapping of the cross-section of a single fiber confirms that the distribution of Pd/C@ Pt-skin catalysts and Nafion1 ionomer matches well in the E-U electrode. The high porosity and large electrochemical surface area (ECSA) of the E-U electrode mitigates the oxygen transfer resistance. The peak power density of the E-U electrode arrives at 0.62 W cm(-2) with a Pt loading of 19 mg cm(-2), which is higher than that of the conventional electrode (0.55 W cm(-2)) with a Pt loading of 100 mg cm(-2). The degradation rate of peak power density of the E-U electrode is only 4.8% after accelerated stability test (AST) for 30000 cyclic voltammetry (CV) cycles, demonstrating a better durability than that of the conventional electrode. The enhanced durability of the E-U electrode is attributed to nanofiber structure and interaction between Pd and Pt in the Pd/C@ Pt-skin catalyst. (C) 2017 Published by Elsevier Ltd.
Language英语
WOS IDWOS:000406762700043
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149818
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Fuel Cell Syst & Engn Lab, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Hong, Shaojing,Hou, Ming,Zhang, Hongjie,et al. A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition[J]. ELECTROCHIMICA ACTA,2017,245:395-401.
APA Hong, Shaojing,Hou, Ming,Zhang, Hongjie,Jiang, Yongyi,Shao, Zhigang,&Yi, Baolian.(2017).A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition.ELECTROCHIMICA ACTA,245,395-401.
MLA Hong, Shaojing,et al."A high-performance PEM fuel cell with ultralow platinum electrode via electrospinning and underpotential deposition".ELECTROCHIMICA ACTA 245(2017):395-401.
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